A facile hydrothermal route to self-assembled ZnGa2O4 particles and their microwave application

被引:20
作者
Lu, Mingjia [1 ]
Ouyan, Xin [1 ]
Wu, Songping [1 ]
Ge, Rongyun [1 ]
Xu, Rui [1 ]
机构
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
关键词
Self-assembly; Porous ZnGa2O4; Hydrothermal route; Dielectric materials/properties; DIELECTRIC-PROPERTIES; SPINEL ZNGA2O4; THIN-FILMS; PHOTOLUMINESCENCE; DEPENDENCE; REDUCTION; CERAMICS; CO;
D O I
10.1016/j.apsusc.2015.12.206
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Self-assembled porous ZnGa2O4 particles were synthesized through a facile hydrothermal route in this work. The phase evolution and microstructure of specimens were identified by XRD and SEM. Various morphologies (i.e. porous, nanorods or spherical particles) and size (nano or micro-sized) could be rationally designed through altering the reaction conditions. Hydrothermal ZnGa2O4 particles exhibited an outstanding microwave dielectric performance, i.e. a dielectric constant of 9.93, a Q x f value of 73 000 GHz, and a tau(f) value of -68.7 ppm/degrees C. What is more, the ZnGa2O4 ceramics displayed a stable quality factor in the high temperature region (1400-1500 degrees C) due to the unique frame-structured ZnGa2O4 particles. Therefore, they can be regarded as potential candidate materials for millimeter-wave device. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:775 / 782
页数:8
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