Density measurements of the binary mixtures of 2-butanone and 2-butanol at temperatures from-10 to 80 °C

被引:20
作者
Faranda, S [1 ]
Foca, G [1 ]
Marchetti, A [1 ]
Pályi, G [1 ]
Tassi, L [1 ]
Zucchi, C [1 ]
机构
[1] Univ Modena & Reggio Emilia, Dept Chem, I-41100 Modena, Italy
关键词
density; excess molar volumes; binary mixtures; 2-butanone; 2-butanol;
D O I
10.1016/j.molliq.2003.12.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Densities of methyl-ethyl-ketone + 2-butanol were measured at temperatures between -10 and 80 degreesC, working with the pure species and nine binary mixtures. At each experimental condition, the data were correlated by means of some empirical equations and according to well-established literature models. The estimated excess molar volumes (and some related quantities) were also evaluated by applying the Redlich-Kister equation. The results related to specific intermolecular interactions have been interpreted in terms of structural and geometrical effects. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:117 / 123
页数:7
相关论文
共 34 条
[1]   ELECTRON-DIFFRACTION STUDY OF ROTATIONAL ISOMERISM OF METHYL ETHYL KETONE [J].
ABE, M ;
KUCHITSU, K ;
SHIMANOU.T .
JOURNAL OF MOLECULAR STRUCTURE, 1969, 4 (2-4) :245-&
[2]  
Atkinson R. S., 1995, STEREOSELECTIVE SYNT
[3]   EVALUATION OF EXCESS ISENTROPIC COMPRESSIBILITIES AND ISOCHORIC HEAT-CAPACITIES [J].
BENSON, GC ;
KIYOHARA, O .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1979, 11 (11) :1061-1064
[4]   Densities, refractive indices and excess properties of mixing of the n-octanol+1,4-dioxane+2-butanol ternary system at 298.15 K [J].
Camacho, AG ;
Postigo, MA ;
Pedrosa, GC ;
Acevedo, IL ;
Katz, M .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2000, 78 (08) :1121-1127
[5]   DENSITIES AND EXCESS MOLAR VOLUMES OF PROPYLENE CARBONATE PLUS LINEAR AND CYCLIC-KETONES AT 298.15 K [J].
COMELLI, F ;
FRANCESCONI, R .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (04) :808-810
[6]   Densities and speeds of sound in the ternary mixture (2-butanol plus n-hexane plus 1-chlorobutane) at 298.15 and 313.15 K [J].
Domínguez, M ;
Martín, S ;
Santafé, J ;
Artigas, H ;
Royo, FM .
THERMOCHIMICA ACTA, 2002, 381 (02) :181-193
[7]  
FIALKOV YY, 1967, RUSS J PHYS CH USSR, V41, P398
[8]   DENSITIES AND REFRACTIVE INDEXES FOR ETHYLENE GLYCOL-WATER SOLUTIONS [J].
FOGG, ET ;
HIXSON, AN ;
THOMPSON, AR .
ANALYTICAL CHEMISTRY, 1955, 27 (10) :1609-1611
[9]   VISCOSITIES OF BINARY LIQUID MIXTURES [J].
FORT, RJ ;
MOORE, WR .
TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (521P) :1112-&
[10]   Conformational studies of 2-butanol using temperature-dependent Raman measurements and MM3 calculations [J].
Hagemann, H ;
Mareda, J ;
Chiancone, C ;
Bill, H .
JOURNAL OF MOLECULAR STRUCTURE, 1997, 410 :357-360