Redox-Responsive Gel-Sol/Sol-Gel Transition in Poly(acrylic acid) Aqueous Solution Containing Fe(III) Ions Switched by Light

被引:247
作者
Peng, Fei [1 ]
Li, Guangzhao [1 ]
Liu, Xinxing [1 ]
Wu, Shuizhu [1 ]
Tong, Zhen [1 ]
机构
[1] S China Univ Technol, Res Inst Mat Sci, Guangzhou 510640, Peoples R China
关键词
D O I
10.1021/ja807087z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Redox-responsive gel-sol/sol-gel transition in aqueous PAA system containing Fe(III)-citrate complex was realized by switching the redox states of Fe(III)/F(II) ions conjugated with photoreduction and oxidation. This reversible transition can be indicated chromatically by the Fe(III) ions and repeated many times as long as there is sufficient citric acid.
引用
收藏
页码:16166 / +
页数:3
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