Characterization and Potential Applications of Hydrochars Derived from P- and N-Enriched Agricultural and Antibiotic Residues via Microwave-Assisted Hydrothermal Conversion

被引:19
作者
Ahmad, Shakeel [1 ,2 ]
Zhu, Xiangdong [1 ,2 ,3 ]
Wei, Xinchao [4 ]
Zhang, Shicheng [1 ,2 ,3 ]
机构
[1] Fudan Univ, Dept Environm Sci & Engn, Shanghai Key Lab Atmospher Particle Pollut & Prev, Shanghai 200438, Peoples R China
[2] Shanghai Tech Serv Platform Pollut Control & Reso, Shanghai 200438, Peoples R China
[3] Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China
[4] Slippery Rock Univ, Sch Engn, Slippery Rock, PA 16057 USA
基金
中国国家自然科学基金;
关键词
SEWAGE-SLUDGE; RAPESEED CAKE; SOLID-FUEL; PHOSPHORUS RELEASE; ALKALI-METALS; TG-FTIR; CARBONIZATION; WASTE; TRANSFORMATION; PYROLYSIS;
D O I
10.1021/acs.energyfuels.0c02149
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The effect of treatment temperature on hydrochars' properties using P- and N-enriched agricultural and antibiotic residues as feedstocks via microwave-assisted hydrothermal conversion (MW-HTC) was investigated in this study. MW-HTC changed the physicochemical properties of hydrochars, nutrient fractions (phosphorus (P) and nitrogen (N)), and surface functional groups which were characterized by various analysis tools. The N contents in hydrochars derived from rapeseed (RS) and lincomycin (LM) residues were 7.26 and 7.76% at 120 degrees C, respectively. At 210 degrees C, those values were reduced to 5.16 and 3.14% accordingly, indicating a higher temperature led to more N release. The speciation of P fractions was affected by temperature, and LM derived hydrochars possessed higher bioavailable P for plants' nutrient uptake. The atomic ratios of H/C and O/C decreased with treatment temperature for both RS and LM derived hydrochars. LM derived hydrochars were thermally more stable than RS derived hydrochars. RS derived hydrochars exhibited better higher heating value (HHV; 22.0-26.8 MJ/kg) while LM derived hydrochars revealed higher fuel ratio (0.47-0.95). MW-HTC offered a viable route for conversion of P- and N-enriched agricultural and antibiotic residues into highly efficient hydrochars for environment-friendly applications.
引用
收藏
页码:11154 / 11164
页数:11
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