Preparation and molecular structure of [Pb2(TNR) (NO3)2(H2O)]

被引：0

作者：

Zhang, TL ^{[1
]}

Yang, YM

Zhang, JG

Shao, B

Yang, L

Yu, KB

机构：

[1] Beijing Inst Technol, Coll Mechanoelect Engn, Beijing 100081, Peoples R China

[2] China Sci Acad, Chengdu Branch, Ctr Anal & Measurement, Chengdu 610041, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 18卷 / 03期

关键词：

lead complex; preparation; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Pb-2(TNR) (NO3)(2)(H2O)] was prepared by reaction of the aqueous solution of lead nitrate and magnesium styphnate. The crystal structure of Pb-2(TNR) (NO3) (2)(H2O) was determined by single crystal diffraction analysis. The crystal is trielinic, space group P (1) over bar with crystal parameters a = 0. 7279 (2) nm, b = 1. 0698 (2) nm, c = 1. 0738(2) nm; alpha = 86. 82(1)degrees, beta = 89.52(2)degrees, gamma = 83.50 (2) degrees; V = 0. 8295 (3) nm(3), Z = 2, D-c = 3. 201g . cm (-3), F(OOO) = 716. The final R value is 0.0358. In the crystal structure, one lead ion was represented by nine coordination geometry; the other was showed as ten coordination geometry.

引用

页码：305 / 308

页数：4