Impact of Various Parameters Over the Adsorption of Polyvinylpyrrolidone onto Kaolin

被引:17
作者
Bhatti, Qaisar Abbas [1 ]
Baloch, Musa Kaleem [1 ]
Schwarz, Simona [2 ]
Petzold, Gudrun [2 ]
机构
[1] Gomal Univ, Dept Chem, Dera Ismail Khan, Pakistan
[2] Leibniz Inst Polymer Schung Dresden eV, Leibniz, Germany
关键词
Adsorption; electrokinetic layer thickness; FT-IR spectra; kaolin; polyvinylpyrrolidone; U.V-spectroscopy; POLYETHYLENE OXIDE; POLYVINYL; BEHAVIOR; DICKITE; ALCOHOL; POLYMER; SILICA;
D O I
10.1080/01932691.2011.629530
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The adsorption of water-soluble polymer, polyvinylpyrrolidone having molecular mass 9.1 +/- 1.43 x 103Kg mole-1 on kaolin has been investigated. The effect of different parameters like pH, molecular mass of polymer and pre-heat treatment on the adsorption of PVP has been deliberated. The 20.7% decrease in adsorption in pH ranging from 210 have been found, which was an indication of the fact that with the increase in pH the kaolin surfaces sites charge amount and ultimately sign changes. Maximum adsorption was observed at pH 5.6 that was also molecular mass dependent. By increasing the pretreatment temperature, the amount of polymer adsorbed was also increased. However, above the specific temperature adsorption of PVP was decreased and attributed to decrease in specific surface area of kaolin.
引用
收藏
页码:1739 / 1745
页数:7
相关论文
共 27 条
[1]  
Adamson A.W., 1979, A Textbook of Physical Chemistry, V2nd
[2]  
Alexandra H., 1997, COLLOID AND SURFACES, V123-124, P515
[3]   INTERACTION OF PRESERVATIVES WITH MACROMOLECULES .5. BINDING OF CHLOROBUTANOL BENZYL ALCOHOL + PHENYLETHYL ALCOHOL NONIONIC AGENTS [J].
BAHAL, CK ;
KOSTENBAUDER, HB .
JOURNAL OF PHARMACEUTICAL SCIENCES, 1964, 53 (09) :1027-&
[4]   Solvent quality and solution behavior of nylon 12 [J].
Baloch, Musa Kaleem ;
Qayum, Munaza ;
Nawaz, Mohsin ;
Akber, Sher .
CHINESE JOURNAL OF POLYMER SCIENCE, 2007, 25 (05) :483-490
[5]   RELATION BETWEEN STRUCTURAL DISORDER AND OTHER CHARACTERISTICS OF KAOLINITES AND DICKITES [J].
BRINDLEY, GW ;
KAO, CC ;
HARRISON, JL ;
LIPSICAS, M ;
RAYTHATHA, R .
CLAYS AND CLAY MINERALS, 1986, 34 (03) :239-249
[6]  
FRANCIS C W, 1973, Soil Science, V115, P40, DOI 10.1097/00010694-197301000-00007
[7]   POLY(N-VINYL-2-PYRROLIDONE) MONOALKYL XANTHATES .1. ADSORPTION AND CHEMICAL-REACTION [J].
GARGALLO, L ;
PEREZCOTAPOS, J ;
SANTOS, JG ;
RADIC, D .
LANGMUIR, 1993, 9 (03) :681-684
[8]   ADSORPTION CHARACTERISTICS OF POLYVINYLPYRROLIDONE AT SOLID-LIQUID INTERFACE [J].
GARGALLO, L ;
CID, E .
COLLOID AND POLYMER SCIENCE, 1977, 255 (06) :556-559
[9]  
Gerg S.J., 1953, JOURNAL OF CHEM SOC, P3951
[10]   ADSORPTION OF POLYVINYL ALCOHOLS BY MONTMORILLONITE [J].
GREENLAND, DJ .
JOURNAL OF COLLOID SCIENCE, 1963, 18 (07) :647-&