Synthesis of porous g-C3N4/La and enhanced photocatalytic activity for the degradation of phenol under visible light irradiation

A series of porous g-C3N4/La (PGCN/La) materials used as photocatalyst for the degradation of phenol were prepared by two steps. The photocatalysts were characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS), thermogravimetry (TG), Brunauer-Emmett-Teller (BET), Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). From the TEM morphology, the porous structure of g-C3N4 could be successfully controlled; from BET results, BET specific surface area of porous g-C3N4 (PGCN) sample increases with the increasing of urea mass ratio. Compared with PGCN material (PGCN-50), PGCN/La sample (PGCN-50/La-5) could exhibit an enhanced photocatalytic activity and has the best degradation efficiency of 98.6% within 50 mm under visible light irradiation. Photocatalytic reaction follows the first-order model kinetics; and PGCN-50/La-5 photocatalyst shows the largest reaction rate among all samples which is nearly 2.96 times higher than that of pure PGCN-50. The present work illustrates that the photocatalytic activity of porous g-C3N4 was improved by the addition of La and PGCN-50/La-5 has potential application in the removal of phenol or other organic molecular from wastewater. (C) 2015 Elsevier Inc. All rights reserved.