Synthesis, structure and physical properties of Ru ferrites:: BaMRu5O11 (M = Li and Cu) and BaM′2Ru4O11 (M′ = Mu, Fe and Co)

被引：54
作者：
Foo, ML
Huang, Q
Lynn, JW
Lee, WL
Klimczuk, T
Hagemann, IS
Ong, NP
Cava, RJ
机构：
[1] Princeton Univ, Dept Chem, Princeton, NJ 08540 USA
[2] NIST, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA
[3] Princeton Univ, Dept Phys, Princeton, NJ 08540 USA
[4] Gdansk Univ Technol, Fac Appl Phys & Math, PL-80952 Gdansk, Poland
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2006年 / 179卷 / 02期
基金：
美国国家科学基金会;
关键词：
R-type ferrite; BaMru(5)O(11) (M = Li; Cu); BaM2Ru4O11 (M = Mn; Fe; Co); Kagome lattice;
D O I：
10.1016/j.jssc.2005.11.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, structure, and physical properties of five R-type Ru ferrites with chemical formula BaMRu5O11 (M = Li and Cu) and BaM'2Ru4O11 (M = Mn, Fe and Co) are reported. All the ferrites crystallize in space group P6(3)/mmc and consist of layers of edge sharing octahedra interconnected by pairs of face sharing octahedra and isolated trigonal bipyramids. For M = Li and Cu, the ferrites are paramagnetic metals with the M atoms found on the trigonal bipyramid sites exclusively. For M' = Mn, Fe and Co, the ferrites are soft ferromagnetic metals. For M' = Mn, the Mn atoms are mixed randomly with Ru atoms on different sites. The magnetic structure for BaMn2Ru4O11 is reported. (C) 2005 Elsevier Inc. All rights reserved.
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收藏
页码：563 / 572
页数：10
相关论文
共 25 条
[1]  
Belov N.V., 1957, Sov. Phys. Crystallogr, V2, P311
[2]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197
[3]   THE CRYSTAL STRUCTURE OF HOLLANDITE, THE RELATED MANGANESE OXIDE MINERALS, AND ALPHA-MNO2 [J].
BYSTROM, A ;
BYSTROM, AM .
ACTA CRYSTALLOGRAPHICA, 1950, 3 (02) :146-154
[4]   REFINEMENTS OF THE 6-LAYER STRUCTURES OF THE R-TYPE HEXAGONAL FERRITES BATI2FE4O11 AND BASN2FE4O11 [J].
CADEE, MC ;
IJDO, DJW .
JOURNAL OF SOLID STATE CHEMISTRY, 1984, 52 (03) :302-312
[5]   Triangular antiferromagnets [J].
Collins, MF ;
Petrenko, OA .
CANADIAN JOURNAL OF PHYSICS, 1997, 75 (09) :605-655
[6]   SYNTHESIS AND CRYSTAL-STRUCTURE OF NAV6O11 [J].
DEROY, ME ;
BESSE, JP ;
CHEVALIER, R ;
GASPERIN, M .
JOURNAL OF SOLID STATE CHEMISTRY, 1987, 67 (01) :185-189
[7]   Magnetic field-tuned quantum criticality in the metallic ruthenate Sr3Ru2O7 [J].
Grigera, SA ;
Perry, RS ;
Schofield, AJ ;
Chiao, M ;
Julian, SR ;
Lonzarich, GG ;
Ikeda, SI ;
Maeno, Y ;
Millis, AJ ;
Mackenzie, AP .
SCIENCE, 2001, 294 (5541) :329-332
[8]   Spin chirality on a two-dimensional frustrated lattice [J].
Grohol, D ;
Matan, K ;
Cho, JH ;
Lee, SH ;
Lynn, JW ;
Nocera, DG ;
Lee, YS .
NATURE MATERIALS, 2005, 4 (04) :323-328
[9]   PREPARATION AND STRUCTURE OF BATI2FE4O11 (R-BLOCK) [J].
HABEREY, F ;
VELICESC.M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, B 30 (JUN15) :1507-1510
[10]   The effect of Ru-site dopants on the magnetic properties of CaRuO3 [J].
He, T ;
Cava, RJ .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2001, 13 (36) :8347-8361
123