Novel nanocomposites based on fatty acid modified cellulose nanofibers/poly(lactic acid): Morphological and physical properties

被引：88
作者：
Almasi, Hadi [1 ]
Ghanbarzadeh, Babak [2 ]
Dehghannya, Jalal [2 ]
Entezami, Ali Akbar [3 ]
Asl, Asghar Khosrowshahi [1 ]
机构：
[1] Univ Urmia, Dept Food Sci & Technol, Fac Agr, Orumiyeh, Iran
[2] Univ Tabriz, Dept Food Sci & Technol, Fac Agr, POB 51666-16471, Tabriz, Iran
[3] Univ Tabriz, Dept Polymer Chem, Fac Chem, Tabriz, Iran
来源：
FOOD PACKAGING AND SHELF LIFE | 2015年 / 5卷
关键词：
Poly(lactic acid); Cellulose nanofibers; Surface modification; Morphological properties; Thermal properties; FIBER SURFACE-TREATMENTS; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; POLY(LACTIC ACID); PLA; WHISKERS; NANOCRYSTALS; COMPOSITES; BARRIER; DEGRADATION;
D O I：
10.1016/j.fpsl.2015.04.003
中图分类号：
TS2 [食品工业];
学科分类号：
0832 ;
摘要：
A novel poly(lactic acid) (PLA) based nanocomposite, reinforced by cellulose nanofibers (CNFs) was prepared. CNFs were previously treated by oleic acid for improving the compatibility with PLA matrix. Resulted modified nanofibers (MCNFs) exhibited reduced surface polarity in comparison to non-modified CNFs. MCNFs were subsequently introduced into PLA matrix and the effects of the CNFs surface modification on morphological, mechanical, thermal and barrier properties of the PLA based nanocomposites were studied. The morphology of fracture surfaces was evaluated by field emission scanning electron microscopy (FE-SEM). Differential scanning calorimetry (DSC) showed that the melting temperatures of the PLA-MCNF nanocomposites were considerably higher than that of the pure PLA film. The ultimate tensile strength and Young's modulus of nanocomposites (at 12% MCNFs) were about 2.5 and 2 times as much as those of the pure PLA films, respectively. In addition, adding MCNFs caused a decrease in water vapor permeability. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：21 / 31
页数：11
相关论文
共 58 条
[21]   Physico-chemical and mechanical properties of nanocomposites prepared using cellulose nanowhiskers and poly(lactic acid) [J].
Hossain, Kazi M. Zakir ;
Ahmed, Ifty ;
Parsons, Andrew J. ;
Scotchford, Colin A. ;
Walker, Gavin S. ;
Thielemans, Wim ;
Rudd, Chris D. .
JOURNAL OF MATERIALS SCIENCE, 2012, 47 (06) :2675-2686
[22]   Solvent-free acetylation of bacterial cellulose under moderate conditions [J].
Hu, Weili ;
Chen, Shiyan ;
Xu, Qiushu ;
Wang, Huaping .
CARBOHYDRATE POLYMERS, 2011, 83 (04) :1575-1581
[23]   Effect of fiber surface-treatments on the properties of laminated biocomposites from poly(lactic acid) (PLA) and kenaf fibers [J].
Huda, Masud S. ;
Drzal, Lawrence T. ;
Mohanty, Amar K. ;
Misra, Manjusri .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (02) :424-432
[24]   Synthesis and characterization of polyvinyl alcohol/nanospherical cellulose particle films [J].
Ibrahim, Maha M. ;
El-Zawawy, Waleed K. ;
Nassar, Mona A. .
CARBOHYDRATE POLYMERS, 2010, 79 (03) :694-699
[25]   Poly-Lactic Acid: Production, Applications, Nanocomposites, and Release Studies [J].
Jamshidian, Majid ;
Tehrany, Elmira Arab ;
Imran, Muhammad ;
Jacquot, Muriel ;
Desobry, Stephane .
COMPREHENSIVE REVIEWS IN FOOD SCIENCE AND FOOD SAFETY, 2010, 9 (05) :552-571
[26]   Thermal degradation behavior of cellulose fibers partially esterified with some long chain organic acids [J].
Jandura, P ;
Riedl, B ;
Kokta, BV .
POLYMER DEGRADATION AND STABILITY, 2000, 70 (03) :387-394
[27]  
Jandura P, 2000, J APPL POLYM SCI, V78, P1354, DOI 10.1002/1097-4628(20001114)78:7<1354::AID-APP60>3.3.CO
[28]  
2-M
[29]   Green nanocomposites based on thermoplastic starch and steam exploded cellulose nanofibrils from wheat straw [J].
Kaushik, Anupama ;
Singh, Mandeep ;
Verma, Gaurav .
CARBOHYDRATE POLYMERS, 2010, 82 (02) :337-345
[30]   Mechanical and thermal properties of PLA composites with cellulose nanofibers and standard size fibers [J].
Kowalczyk, M. ;
Piorkowska, E. ;
Kulpinski, P. ;
Pracella, M. .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2011, 42 (10) :1509-1514
123456