A comparative study on fabrication of a highly effective corrosion protective system based on graphene oxide-polyaniline nanofibers/epoxy composite

被引:201
作者
Hayatgheib, Y. [1 ]
Ramezanzadeh, B. [1 ]
Kardar, P. [1 ]
Mandavian, M. [1 ]
机构
[1] ICST, Dept Surface Coatings & Corros, PO 16765-654, Tehran, Iran
关键词
Steel; XRD; TEM; EIS; Polymer coatings; MILD-STEEL; NANOSHEETS; BARRIER; IRON; RESISTANCE; REDUCTION; GRAPHITE; BEHAVIOR; LAYER;
D O I
10.1016/j.corsci.2018.01.046
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Graphene oxide nanosheets were functionalized with polyaniline (PANI) nanofibers through three methods In method II the polymerization of aniline was done in the presence of sodium dodecyl sulfate as a surfactant and ammonium persulfate as an initiator. In method I the surfactant and in method III the initiator were eliminated during polymerization procedure. The morphology and chemistry of the nanosheets were characterized. Then, the GO/epoxy and GO-PANIs/epoxy nanocomposites were fabricated and their corrosion protection performance was studied on steel substrate by electrochemical impedance spectroscopy. Results revealed that GO-PANI remarkably improved the barrier performance and provided active inhibition for epoxy coating.
引用
收藏
页码:358 / 373
页数:16
相关论文
共 56 条
[1]   The effect of heat treatment on formation of graphene thin films from graphene oxide nanosheets [J].
Akhavan, O. .
CARBON, 2010, 48 (02) :509-519
[2]  
[Anonymous], 1999, CONDUCTING POLYM FUN
[3]   Polyaniline layer for iron protection in sulfate medium [J].
Bernard, MC ;
Hugot-Le Goff, A ;
Joiret, S ;
Dinh, NN ;
Toan, NN .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (03) :995-998
[4]   Protection of iron against corrosion using a polyaniline layer I. Polyaniline electrodeposit [J].
Bernard, MC ;
Joiret, S ;
Hugot-Le Goff, A ;
Phong, PV .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (01) :B12-B16
[5]   Kinetic properties of layer-by-layer assembled cerium zinc molybdate nanocontainers during, corrosion inhibition [J].
Bhanvase, B. A. ;
Patel, M. A. ;
Sonawane, S. H. .
CORROSION SCIENCE, 2014, 88 :170-177
[6]   Graphene materials with different structures prepared from the same graphite by the Hummers and Brodie methods [J].
Botas, Cristina ;
Alvarez, Patricia ;
Blanco, Patricia ;
Granda, Marcos ;
Blanco, Clara ;
Santamaria, Ricardo ;
Romasanta, Laura J. ;
Verdejo, Raquel ;
Lopez-Manchado, Miguel A. ;
Menendez, Rosa .
CARBON, 2013, 65 :156-164
[7]   Impermeable atomic membranes from graphene sheets [J].
Bunch, J. Scott ;
Verbridge, Scott S. ;
Alden, Jonathan S. ;
van der Zande, Arend M. ;
Parpia, Jeevak M. ;
Craighead, Harold G. ;
McEuen, Paul L. .
NANO LETTERS, 2008, 8 (08) :2458-2462
[8]   Oxidation Resistance of Graphene-Coated Cu and Cu/Ni Alloy [J].
Chen, Shanshan ;
Brown, Lola ;
Levendorf, Mark ;
Cai, Weiwei ;
Ju, Sang-Yong ;
Edgeworth, Jonathan ;
Li, Xuesong ;
Magnuson, Carl W. ;
Velamakanni, Aruna ;
Piner, Richard D. ;
Kang, Junyong ;
Park, Jiwoong ;
Ruoff, Rodney S. .
ACS NANO, 2011, 5 (02) :1321-1327
[9]   High Throughput Exfoliation of Graphene Oxide from Expanded Graphite with Assistance of Strong Oxidant in Modified Hummers Method [J].
Chen, T. ;
Zeng, Baoqing ;
Liu, J. L. ;
Dong, J. H. ;
Liu, X. Q. ;
Wu, Z. ;
Yang, X. Z. ;
Li, Z. M. .
8TH CHINA INTERNATIONAL NANOSCIENCE AND TECHNOLOGY SYMPOSIUM (CINSTS09), 2009, 188
[10]   MODIFICATION OF THE ELECTROCHEMICAL AND CORROSION BEHAVIOR OF STAINLESS-STEELS WITH AN ELECTROACTIVE COATING [J].
DEBERRY, DW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (05) :1022-1026