A rapid solid-phase synthesis to soluble oligothiophene molecular wires

被引:0
作者
Zhang, HM [1 ]
Wang, XH [1 ]
Zhao, XJ [1 ]
Li, J [1 ]
Wang, FS [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Mat Engn Lab, Changchun 130022, Peoples R China
关键词
solid-phase synthesis; molecular wires; oligothiophene;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel method for the preparation of oligothiophene molecular wires is described via a bi-directional solid-phase synthesis. Using an alternating sequence of bromination and Stille coupling reactions, oligomers were obtained up to the heptamer in excellent yield and purity.
引用
收藏
页码:437 / 440
页数:4
相关论文
共 14 条
[1]  
Bräse S, 2000, CHEM-EUR J, V6, P1899, DOI 10.1002/1521-3765(20000602)6:11<1899::AID-CHEM1899>3.0.CO
[2]  
2-M
[3]   A novel solid-phase synthesis of highly diverse guanidines:: Reactions of primary amines attached to the T2*linker [J].
Dahmen, S ;
Bräse, S .
ORGANIC LETTERS, 2000, 2 (23) :3563-3565
[4]   ELECTRONIC-ENERGY TRANSFER ACROSS ETHYNYL-BRIDGED RU-II/OS-II TERPYRIDYL COMPLEXES [J].
GROSSHENNY, V ;
HARRIMAN, A ;
ZIESSEL, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (10) :1100-1102
[5]   Synthesis and polymerization of 3,3′-dialkyl-2,2′-bithiophenes [J].
Hoffmann, KJ ;
Bakken, E ;
Samuelsen, EJ ;
Carlsen, PHJ .
SYNTHETIC METALS, 2000, 113 (1-2) :39-44
[6]  
LEROY JI, 1997, J ORG CHEM, V62, P1388
[7]   Effect of chromium content on structure and mechanical properties of Ti-7.5Mo-xCr alloys [J].
Lin, DJ ;
Lin, JHC ;
Ju, CP .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2003, 14 (01) :1-7
[8]  
Martin RE, 1999, ANGEW CHEM INT EDIT, V38, P1350, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1350::AID-ANIE1350>3.0.CO
[9]  
2-6
[10]   Solid-phase synthesis of phenylacetylene oligomers utilizing a novel 3-propyl-3-(benzyl-supported) triazene linkage [J].
Nelson, JC ;
Young, JK ;
Moore, JS .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (23) :8160-8168