Reductive elimination: a pathway to low-valent aluminium species

被引：80
|
作者：
Ganesamoorthy, Chelladurai [1 ]
Loerke, Sinah [1 ]
Gemel, Christian [1 ]
Jerabek, Paul [2 ]
Winter, Manuela [1 ]
Frenking, Gernot [2 ]
Fischer, Roland A. [1 ]
机构：
[1] Ruhr Univ Bochum, D-44801 Bochum, Germany
[2] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 28期
关键词：
CHEMICAL-VAPOR-DEPOSITION; METAL-HYDRIDES; REACTIVITY; CHEMISTRY; MATRIX; HYDROALUMINATION; DERIVATIVES; COMPOUND;
D O I：
10.1039/c3cc38584a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Compounds Cp*AlH2 (1) and Cp-2*AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.
引用
收藏
页码：2858 / 2860
页数：3
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