Reductive elimination: a pathway to low-valent aluminium species

被引：80

作者：

Ganesamoorthy, Chelladurai ^{[1
]}

Loerke, Sinah ^{[1
]}

Gemel, Christian ^{[1
]}

Jerabek, Paul ^{[2
]}

Winter, Manuela ^{[1
]}

Frenking, Gernot ^{[2
]}

Fischer, Roland A. ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44801 Bochum, Germany

[2] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 28期

关键词：

CHEMICAL-VAPOR-DEPOSITION; METAL-HYDRIDES; REACTIVITY; CHEMISTRY; MATRIX; HYDROALUMINATION; DERIVATIVES; COMPOUND;

D O I：

10.1039/c3cc38584a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compounds Cp*AlH2 (1) and Cp-2*AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.

引用

页码：2858 / 2860

页数：3

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