Liquid phase exfoliation of carbonate-intercalated layered double hydroxides

被引:59
作者
Carrasco, Jose A. [1 ]
Harvey, Andrew [2 ,3 ,4 ]
Hanlon, Damien [2 ,3 ,4 ]
Lloret, Vicent [5 ]
McAteer, Dave [2 ,3 ,4 ]
Sanchis-Gual, Roger [1 ]
Hirsch, Andreas [5 ]
Hauke, Frank [5 ]
Abellan, Gonzalo [1 ,5 ]
Coleman, Jonathan N. [2 ,3 ,4 ]
Coronado, Eugenio [1 ]
机构
[1] Univ Valencia, Inst Ciencia Mol, Catedrat Jose Beltran 2, Paterna 46980, Spain
[2] Trinity Coll Dublin, Sch Phys, Dublin 2, Ireland
[3] Trinity Coll Dublin, CRANN Ctr, Dublin 2, Ireland
[4] Trinity Coll Dublin, AMBER Res Ctr, Dublin 2, Ireland
[5] Univ Erlangen Nurnberg, Dept Chem & Pharm, Henkestr 42, D-91054 Erlangen, Germany
基金
爱尔兰科学基金会; 欧洲研究理事会;
关键词
ANION-EXCHANGE; NANOSHEETS; DELAMINATION;
D O I
10.1039/c9cc00197b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Direct exfoliation of a carbonate layered double hydroxide (LDH) has been achieved by using a novel horn-probe sonic tip, avoiding the development of time-consuming anion-exchange reactions. The most suitable solvents were chosen based on the Hildebrand solubility parameters and the thickness of the exfoliated nanosheets confirmed unambiguously the successful delamination.
引用
收藏
页码:3315 / 3318
页数:4
相关论文
共 33 条
[1]   Hybrid Materials Based on Magnetic Layered Double Hydroxides: A Molecular Perspective [J].
Abellan, Gonzalo ;
Marti-Gastaldo, Carlos ;
Ribera, Antonio ;
Coronado, Eugenio .
ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (06) :1601-1611
[2]   Stimuli-responsive hybrid materials: breathing in magnetic layered double hydroxides induced by a thermoresponsive molecule [J].
Abellan, Gonzalo ;
Luis Jorda, Jose ;
Atienzar, Pedro ;
Varela, Maria ;
Jaafar, Miriam ;
Gomez-Herrero, Julio ;
Zamora, Felix ;
Ribera, Antonio ;
Garcia, Hermenegildo ;
Coronado, Eugenio .
CHEMICAL SCIENCE, 2015, 6 (03) :1949-1958
[3]   Hexagonal nanosheets from the exfoliation of Ni2+-Fe3+ LDHs: a route towards layered multifunctional materials [J].
Abellan, Gonzalo ;
Coronado, Eugenio ;
Marti-Gastaldo, Carlos ;
Pinilla-Cienfuegos, Elena ;
Ribera, Antonio .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (35) :7451-7455
[4]   Guidelines for Exfoliation, Characterization and Processing of Layered Materials Produced by Liquid Exfoliation [J].
Backes, Claudia ;
Higgins, Thomas M. ;
Kelly, Adam ;
Boland, Conor ;
Harvey, Andrew ;
Hanlon, Damien ;
Coleman, Jonathan N. .
CHEMISTRY OF MATERIALS, 2017, 29 (01) :243-255
[5]   Production of Highly Monolayer Enriched Dispersions of Liquid-Exfoliated Nanosheets by Liquid Cascade Centrifugation [J].
Backes, Claudia ;
Szydlowska, Beata M. ;
Harvey, Andrew ;
Yuan, Shengjun ;
Vega-Mayoral, Victor ;
Davies, Ben R. ;
Zhao, Pei-liang ;
Hanlon, Damien ;
Santos, Elton J. G. ;
Katsnelson, Mikhail I. ;
Blau, Werner J. ;
Gadermaier, Christoph ;
Coleman, Jonathan N. .
ACS NANO, 2016, 10 (01) :1589-1601
[6]   Deciphering the Role of Dipolar Interactions in Magnetic Layered Double Hydroxides [J].
Carrasco, Jose A. ;
Cardona-Serra, Salvador ;
Modesto Clemente-Juan, Juan ;
Gaita-Arino, Alejandro ;
Albellan, Gonzalo ;
Coronado, Eugenio .
INORGANIC CHEMISTRY, 2018, 57 (04) :2013-2022
[7]   Influence of morphology in the magnetic properties of layered double hydroxides [J].
Carrasco, Jose A. ;
Abellan, Gonzalo ;
Coronado, Eugenio .
JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (05) :1187-1198
[8]   Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts [J].
Carrasco, Jose A. ;
Romero, Jorge ;
Varela, Maria ;
Hauke, Frank ;
Abellan, Gonzalo ;
Hirsch, Andreas ;
Coronado, Eugenio .
INORGANIC CHEMISTRY FRONTIERS, 2016, 3 (04) :478-487
[9]  
Forano C, 2006, DEV CLAY SCI, V1, P1021, DOI 10.1016/S1572-4352(05)01039-1
[10]   Few-Layer Antimonene by Liquid-Phase Exfoliation [J].
Gibaja, Carlos ;
Rodriguez-San-Miguel, David ;
Ares, Pablo ;
Gomez-Herrero, Julio ;
Varela, Maria ;
Gillen, Roland ;
Maultzsch, Janina ;
Hauke, Frank ;
Hirsch, Andreas ;
Abellan, Gonzalo ;
Zamora, Felix .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (46) :14343-14347