Effects of cations and anions of ionic liquids on the production of 5-hydroxymethylfurfural from fructose

被引：95

作者：

Shi, Chunyan ^{[1
]}

Zhao, Yuling ^{[2
]}

Xin, Jiayu ^{[1
]}

Wang, Jinquan ^{[1
]}

Lu, Xingmei ^{[1
]}

Zhang, Xiangping ^{[1
]}

Zhang, Suojiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China

[2] Henan Normal Univ, Key Lab Green Chem Media & React, Minist Educ, Sch Chem & Environm Sci, Xinxiang 453007, Henan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 34期

基金：

中国国家自然科学基金;

关键词：

CATALYTIC CONVERSION; DEHYDRATION; BIOMASS; SUGARS;

D O I：

10.1039/c2cc30357d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids (ILs) with different cations and anions were used to study the effects on 5-hydroxymethylfurfural (HMF) preparation. It was found that both aggregations of cations and hydrogen bonds of anions with fructose played important roles. Molecular dynamics simulations were also performed to explain the experimental results.

引用

页码：4103 / 4105

页数：3

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