Refractive indices of water and aqueous electrolyte solutions under high magnetic fields

被引:124
作者
Hosoda, H [1 ]
Mori, H [1 ]
Sogoshi, N [1 ]
Nagasawa, A [1 ]
Nakabayashi, S [1 ]
机构
[1] Saitama Univ, Fac Sci, Dept Chem, Sakura Ku, Urawa, Saitama, Japan
关键词
D O I
10.1021/jp0310145
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The refractive index of water was measured at atmospheric pressure under magnetic fields up to 10 T and found to increase by similar to0.1% with increasing magnetic field strength. In contrast, the refractive index of saturated aqueous electrolyte solutions decreased under the magnetic field. In the case of n-hexane, any change of the optical property by the magnetic field was not found. A possible explanation is that the lifetime of the hydrogen bond is prolonged due to the electron delocalization of a water dimer under the magnetic field.
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页码:1461 / 1464
页数:4
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