Structures and magnetic properties of two noncentrosymmetric coordination polymers based on carboxyphosphinate ligand

被引：11

作者：

Li, Jianyong ^{[1
]}

Xue, Chao-Chao ^{[2
]}

Liu, Siming ^{[4
]}

Wang, Zhao-Xi ^{[2
,3
]}

机构：

[1] Nanchang Univ, Coll Basic Med, Nanchang 330006, Peoples R China

[2] Shanghai Univ, Dept Chem, Innovat Drug Res Ctr, Shanghai 200444, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[4] Ulink Coll Shanghai, Shanghai 201617, Peoples R China

来源：

SOLID STATE SCIENCES | 2016年 / 61卷

基金：

中国国家自然科学基金; 上海市自然科学基金;

关键词：

Copper(II); Manganese(II); Noncentrosymmetric; Carboxyphosphinate ligand; Magnetic properties; METAL-ORGANIC FRAMEWORKS; SECONDARY BUILDING UNITS; CRYSTAL-STRUCTURES; 2-CARBOXYETHYL(PHENYL)PHOSPHINATE LIGAND; LANTHANIDE PHOSPHONATES; LUMINESCENT PROPERTIES; LAYER STRUCTURES; COMPLEXES; ACID; NETWORKS;

D O I：

10.1016/j.solidstatesciences.2016.09.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel coordination polymers have been hydrothermally synthesized by reactions of Cu(II), Mn(II) salt with 2-carboxyethyl(phenyl)phosphinic acid (H2L), namely, [Cu(L)(H2O)](n) (1) and [Mn(HL)(2)](n) (2). Both compounds were well characterized by single crystal X-ray diffraction, elemental analysis, IR spectroscopic, power X-ray diffraction and magnetic studies. Compound 1 crystallizes in a non-centrosymmetric monoclinic Cc space group and presents an inorganic two-dimensional (2D) network, whereas compound 2 adopts a noncentrosymmetric Pca2(1) space group and exhibits a 2D layer structure. Magnetic studies reveal a dominant ferromagnetic interaction in 1, and weak antiferromagnetic coupling between the Mn(II) ions in 2 mediated by phosphinico group, respectively. (C) 2016 Elsevier Masson SAS. All rights reserved.

引用

页码：111 / 115

页数：5

共 58 条

[1] Oligonuclear complexes as tectons in crystal engineering: structural diversity and magnetic properties [J].

Andruh, Marius .

CHEMICAL COMMUNICATIONS, 2007, (25) :2565-2577

[2] Compartmental Schiff-base ligands-a rich library of tectons in designing magnetic and luminescent materials [J].

Andruh, Marius .

CHEMICAL COMMUNICATIONS, 2011, 47 (11) :3025-3042

[3] Co-Ca Phosphonate Showing Humidity-Sensitive Single Crystal to Single Crystal Structural Transformation and Tunable Proton Conduction Properties [J].

Bao, Song-Song ;

Li, Nan-Zhu ;

Taylor, Jared M. ;

Shen, Yang ;

Kitagawa, Hiroshi ;

Zheng, Li-Min .

CHEMISTRY OF MATERIALS, 2015, 27 (23) :8116-8125

[4]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[5]

2-Z

[6] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[7] Vertex-, face-, point-, Schlafli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology [J].

Blatov, V. A. ;

O'Keeffe, M. ;

Proserpio, D. M. .

CRYSTENGCOMM, 2010, 12 (01) :44-48

[8]

Blatov V. A., 2006, IUCr CompComm Newsletter, V7, P4, DOI DOI 10.1039/B807165A

[9] TOPOS3.2:: A new version of the program package for multipurpose crystal-chemical analysis [J].

Blatov, VA ;

Shevchenko, AP ;

Serezhkin, VN .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2000, 33 :1193-1193

[10] Luminescence of lanthanides in covalently pillared zirconium phosphate [J].

Brunet, Ernesto ;

Alhendawi, Hussein M. H. ;

Juanes, Olga ;

Jimenez, Laura ;

Carlos Rodriguez-Ubis, Juan .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (17) :2494-2502

← 1 2 3 4 5 6 →