2-methyl-1,4-naphthoquinones containing 3-[N-(ω-mercaptoalkyl)alkanamide] chains:: synthesis, self-assembling, and electrochemical properties

被引：6

作者：

Kazemekaite, Maryte ^{[1
]}

Bulovas, Arunas ^{[1
]}

Talaikyte, Zita ^{[1
]}

Railaite, Vilma ^{[1
,2
]}

Niaura, Gediminas ^{[1
]}

Butkus, Eugenijus ^{[2
]}

Razumas, Valdemaras ^{[1
]}

机构：

[1] Inst Biochem, Dept Bioelectrochem & Biospectroscopy, LT-08662 Vilnius, Lithuania

[2] Vilnius State Univ, Dept Organ Chem, LT-03225 Vilnius, Lithuania

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 43期

关键词：

D O I：

10.1016/j.tetlet.2008.08.039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Methyl-1,4-naphthoquinone derivatives containing 3-[N-(omega-mercaptoalkyl)alkanamide] chains were synthesized from omega-bromoalkylamine salts of 2-methyl-3-carboxyalkyl-1,4-naphthoquinones in the presence of N,N '-dicyclohexylcarbodiimide at ambient temperature, and then transformed into the corresponding mercapto derivatives. Their self-assembling and electrochemical Properties on gold were studied. The influence of an intrachain amide group on the Structure and electron transfer properties of self-assembled monolayers were evaluated by comparison with analogous ester and alkyl chain-containing 2-methyl-1,4-naphthoquinones. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：6212 / 6216

页数：5

共 15 条

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