2-methyl-1,4-naphthoquinones containing 3-[N-(ω-mercaptoalkyl)alkanamide] chains:: synthesis, self-assembling, and electrochemical properties

被引：6
|
作者：
Kazemekaite, Maryte [1 ]
Bulovas, Arunas [1 ]
Talaikyte, Zita [1 ]
Railaite, Vilma [1 ,2 ]
Niaura, Gediminas [1 ]
Butkus, Eugenijus [2 ]
Razumas, Valdemaras [1 ]
机构：
[1] Inst Biochem, Dept Bioelectrochem & Biospectroscopy, LT-08662 Vilnius, Lithuania
[2] Vilnius State Univ, Dept Organ Chem, LT-03225 Vilnius, Lithuania
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 43期
关键词：
D O I：
10.1016/j.tetlet.2008.08.039
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
2-Methyl-1,4-naphthoquinone derivatives containing 3-[N-(omega-mercaptoalkyl)alkanamide] chains were synthesized from omega-bromoalkylamine salts of 2-methyl-3-carboxyalkyl-1,4-naphthoquinones in the presence of N,N '-dicyclohexylcarbodiimide at ambient temperature, and then transformed into the corresponding mercapto derivatives. Their self-assembling and electrochemical Properties on gold were studied. The influence of an intrachain amide group on the Structure and electron transfer properties of self-assembled monolayers were evaluated by comparison with analogous ester and alkyl chain-containing 2-methyl-1,4-naphthoquinones. (C) 2008 Elsevier Ltd. All rights reserved.
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收藏
页码：6212 / 6216
页数：5
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