Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)-H Borylation of Methylchlorosilanes

被引：85

作者：

Ohmura, Toshimichi ^{[1
]}

Torigoe, Takeru ^{[1
]}

Suginome, Michinori ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 42期

关键词：

C-H BONDS; REGIOSPECIFIC FUNCTIONALIZATION; UNACTIVATED C(SP(3))-H; ACTIVATION; ARENES; ROUTE; CARBONYLATION; COMPLEXES; SCAFFOLDS; MECHANISM;

D O I：

10.1021/ja307956w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 degrees C, giving (borylmethyl)chlorosilanes selectively.

引用

页码：17416 / 17419

页数：4

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