Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)-H Borylation of Methylchlorosilanes

被引：85
作者：
Ohmura, Toshimichi [1 ]
Torigoe, Takeru [1 ]
Suginome, Michinori [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 42期
关键词：
C-H BONDS; REGIOSPECIFIC FUNCTIONALIZATION; UNACTIVATED C(SP(3))-H; ACTIVATION; ARENES; ROUTE; CARBONYLATION; COMPLEXES; SCAFFOLDS; MECHANISM;
D O I：
10.1021/ja307956w
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 degrees C, giving (borylmethyl)chlorosilanes selectively.
引用
收藏
页码：17416 / 17419
页数：4
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