Synthesis and structural characterisation of stable pyridine- and phosphine-functionalised N-heterocyclic carbenes

被引：79

作者：

Danopoulos, AA ^{[1
]}

Winston, S

Gelbrich, T

Hursthouse, MB

Tooze, RP

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[2] ICI Synetix, Billingham TS23 1LB, Cleveland, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 05期

关键词：

D O I：

10.1039/b111659b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable, uncoordinated {1-[2-(6-trimethylsilyl) pyridyl] 3-[( 2,6-diisopropyl) phenyl] imidazol-2-ylidene}, I, and {1-[beta ( diphenylphosphino) ethyl]-3-[(2,6-diisopropyl) phenyl] imidazol-2-ylidene}, II, have been synthesised; in the solid state they adopt a conformation with the lone pairs in a mutually anti arrangement.

引用

页码：482 / 483

页数：2

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