Scale-invariant growth of fractal aggregates

被引:7
作者
Gmachowski, L [1 ]
机构
[1] Warsaw Univ Technol, Inst Chem, PL-09400 Plock, Poland
[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
aggregate growth; aggregation act; scale-invariant growth; aerosol aggregates; cluster-cluster aggregation;
D O I
10.1016/j.colsurfa.2005.09.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fractal dimension of a formed aggregate depends on the masses and fractal dimensions of approaching clusters as well as on the degree of their mutual penetration. The relations are described by the aggregation act equation. Aggregation act equation is used to analyze the structure of growing fractal aggregates. If the coagulating aggregates have the same fractal dimension, the appropriate choice of the ratio of their radii makes it possible to save fractal dimension for the resultant aggregate. The more close to unity the ratio, the lower is the value of fractal dimension. Especially, if the aggregating clusters have the same mass, they grow by the hierarchical cluster-cluster mechanism, for which the constant fractal dimension has the lowest value possible. Some experimental data are quoted to Support the obtained dependences. Using these data, the aggregation act equation is verified to provide the reliable Values of fractal dimension of some aggregates formed by two clusters of comparable aerodynamic diameters. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:223 / 228
页数:6
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