A novel crystal coexisting with two kinds of polyoxomolybdates:: [n-Bu4N]8[Mo6O19]2[α-(Mo8O26]

被引：28
|
作者：
Shi, YP
Yang, W
Xue, GL [1 ]
Hu, HM
Wang, H
机构：
[1] NW Univ Xian, Dept Chem, Shaanxi Key Lab Physicoinorgan Chem, Xian 710069, Peoples R China
[2] Yantan Univ, Dept Chem, Xian 716000, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2006年 / 784卷 / 1-3期
关键词：
polyoxometalates; crystal engineering; crystal structure; molybdenum;
D O I：
10.1016/j.molstruc.2005.09.012
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel polyoxomolybdate, [n-Bu4N](8)[Mo6O19](2)[alpha-(Mo8O26)] (1), has been synthesized and structurally characterized by elemental analysis, IR, TG analysis and single-crystal X-ray diffraction. Compound I represents a rare example coexisting with two kinds of polyoxomolybdate anions in the same crystal architecture. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：244 / 248
页数：5
相关论文
共 50 条
  • [41] A pure inorganic 1D chain based on {Mo8O28} clusters and Mn(II) ions: [Mn(H2O)2Mo8O28]n6n-
    Zhang, Xiaofen
    Yan, Yonghong
    Wu, Lizhou
    Yu, Chengxin
    Dong, Xinbo
    Hu, Huaiming
    Xue, Ganglin
    SOLID STATE SCIENCES, 2016, 51 : 18 - 23
  • [42] Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W)
    M. A. Mikhailov
    A. L. Gushchin
    M. R. Gallyamov
    A. V. Virovets
    M. N. Sokolov
    D. G. Sheven’
    V. V. Pervukhin
    Russian Journal of Coordination Chemistry, 2017, 43 : 172 - 180
  • [43] Synthesis and structural characterization of (C14H16N2)3(C14H17N2)2[β-Mo8O26]
    Zebiri, Ikram
    Boufas, Sihem
    Mosbah, Salima
    Bencharif, Leila
    Bencharif, Mustapha
    JOURNAL OF CHEMICAL SCIENCES, 2015, 127 (10) : 1769 - 1775
  • [44] Hexa- to Octamolybdate Rearrangement leads to the New Coordination Polymer [Ag(PhCN)(thb)]4[β-Mo8O26](PhCN)2
    Kulikov, Vladislav
    Meyer, Gerd
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (01): : 19 - 22
  • [45] Synthesis and structural characterization of (C14H16N2)3(C14H17N2)2[β-Mo8O26]
    IKRAM ZEBIRI
    SIHEM BOUFAS
    SALIMA MOSBAH
    LEÏLA BENCHARIF
    MUSTAPHA BENCHARIF
    Journal of Chemical Sciences, 2015, 127 : 1769 - 1775
  • [46] Hydrothermal Synthesis and Crystal Structure of a Hybrid Compound Based on β-Octamolybdate [Mn（2,2’-bipy）3]2[β-Mo8O26]·4H2O
    SHEN Yue YU Li NIU Jing-Yang WANG Jing-Ping② (School of Chemistry and Chemical Engineering
    结构化学, 2005, (10) : 1164 - 1168
  • [47] Synthesis and structure of paramagnetic β-octamolybdate complex, [Fe(2,2′-bipy)3]2[Mo8O26]•6H2O
    Song, LJ
    Zeng, HY
    Dong, ZC
    Guo, GC
    Huang, JS
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (02) : 135 - 140
  • [48] Hydrothermal synthesis and crystal structure of a hybrid compound based on β-octamolybdate [Mn(2,2β-bipy)3]2[β-Mo8O26]•4H2O
    Shen, Y
    Yu, L
    Niu, JY
    Wang, JP
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (10) : 1164 - 1168
  • [49] Composite solids constructed from one-dimensional coordination polymer matrices and molybdenum oxide subunits: Polyoxomolybdate clusters within [{Cu(4,4'-bpy)}(4)Mo8O26] and [{Ni(H2O)(2)(4,4'-bpy)(2)}(2)Mo8O26] and one-dimensional oxide chains in [{Cu(4,4'-bpy)}(4)Mo15O47]center dot 8H(2)O
    Hagrman, D
    Zubieta, C
    Rose, DJ
    Zubieta, J
    Haushalter, RC
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (08): : 873 - 876
  • [50] Hydrogen Bonding Deduced α and β Polymorphs of Bis(tetrabutylammonium) Bis(cyclohexylammoinum) β-Octamolybdate, [β-Mo8O26]4-
    Wei, Wenhui
    Yin, Panchao
    Wei, Zheyu
    Hao, Jian
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (03) : 364 - 369
12345