Viscosity and surface tension of binary systems of N,N-dimethylformamide with alkan-1-ols at different temperatures

被引：32

作者：

Mohammad, Abubaker A. ^{[1
]}

Alkhaldi, Khaled H. A. E. ^{[1
]}

AlTuwaim, Mohammad S. ^{[1
]}

Al-Jimaz, Adel S. ^{[1
]}

机构：

[1] Coll Technol Studies, Dept Chem Engn, Shuwaikh 70654, Kuwait

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2013年 / 56卷

关键词：

Viscosity; Surface tension; N; N-dimethylformamide; alkan-1-ols; EXCESS MOLAR VOLUMES; CARBON-TETRACHLORIDE; REFRACTIVE-INDEXES; SOLVENT SYSTEMS; VISCOUS-FLOW; 298.15; K; MIXTURES; DENSITIES; METHANOL; ETHANOL;

D O I：

10.1016/j.jct.2012.06.023

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Viscosity eta and surface tension sigma were measured for binary mixtures of N,N-dimethylformamide DMF with pentan-1-ol, hexan-1-ol, and heptan-1-ol at T = (298.15, 303.15, 308.15, and 313.15) K and atmospheric pressure over the entire mole fraction range. Deviations in viscosity Delta eta and surface tension Delta sigma were calculated using experimental results. Moreover, the values of the excess Gibbs free energy of activation G*(E), surface enthalpy H-sigma and surface entropy S-sigma of these mixtures were determined. Viscosity measurements of the binary systems were correlated with Grunberg and Nissan, the three-body and four-body McAllister expressions. Viscosity deviation, surface tension deviation and excess Gibbs energy of activation functions were fitted to the method of Redlich-Kister (R-K) polynomial to estimate the coefficients and standard deviations. The effects of chain length of alkan-1-ols and temperature on the thermodynamic properties of binary systems were studied. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：106 / 113

页数：8

共 34 条

[1] Acoustical and excess properties of {chlorobenzene plus 1-hexanol, or 1-heptanol, or 1-octanol, or 1-nonanol, or 1-decanol} at (298.15, 303.15, 308.15, and 313.15) K
Al-Jimaz, Adel S.
Al-Kandary, Jasem A.
Abdul-Latif, Abdul-Haq M.
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (01) : 206 - 214
[2] Densities and viscosities for binary mixtures of phenetole with 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, 1-nonanol, and 1-decanol at different temperatures
Al-Jimaz, AS
Al-Kandary, JA
Abdul-Latif, AHM
[J]. FLUID PHASE EQUILIBRIA, 2004, 218 (02) : 247 - 260
[3] Al-Kandary J.A., 2009, J PHYS CHEM-US, V47, P210
[4] Comparative study of physico-chemical properties of binary mixtures of N,N-dimethylformamide with 1-alkanols at different temperatures
AlTuwaim, Mohammad S.
Alkhaldi, Khaled H. A. E.
Al-Jimaz, Adel S.
Mohammad, Abubaker A.
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2012, 48 : 39 - 47
[5] DENSITIES, SHEAR VISCOSITIES, REFRACTIVE-INDEXES, AND SPEEDS OF SOUND OF BIS(2-METHOXYETHYL) ETHER WITH HEXANE, HEPTANE, OCTANE, AND 2,2,4-TRIMETHYLPENTANE IN THE TEMPERATURE INTERVAL 298.15-K-318.15-K
AMINABHAVI, TM
ARALAGUPPI, MI
GOPALAKRISHNA, B
KHINNAVAR, RS
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (03) : 522 - 528
[6] EVALUATION OF EXCESS PARAMETERS FROM DENSITIES AND VISCOSITIES OF BINARY-MIXTURES OF ETHANOL WITH ANISOLE, N,N-DIMETHYLFORMAMIDE, CARBON-TETRACHLORIDE, AND ACETOPHENONE FROM 298.15 TO 313.15K
AMINABHAVI, VA
AMINABHAVI, TM
BALUNDGI, RH
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1990, 29 (10) : 2106 - 2111
[7] [Anonymous], 1986, PHYS PROPERTIES METH
[8] [Anonymous], 2003, EV THERM PROP PUR CH
[9] [Anonymous], 1996, TRC TABL SOURC DAT C
[10] Thermodynamic behavior of mixtures .4. Mixtures of methanol with pyridine and N,N-dimethylformamide at 25 degrees C
Bakshi, MS
Kaur, G
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1997, 42 (02) : 298 - 300

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