Room temperature aqueous synthesis of UiO-66 derivatives via postsynthetic exchange

被引：21

作者：

Kalaj, Mark ^{[1
]}

Prosser, Kathleen L. ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92023 USA

来源：

DALTON TRANSACTIONS | 2020年 / 49卷 / 26期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; CHEMISTRY; DESIGN; LIGAND;

D O I：

10.1039/d0dt01939a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, we report the room temperature aqueous synthesis of the Zr(iv)-based metal-organic framework UiO-66 and a series of functionalized derivatives through postsynthetic exchange from a perfluorinated UiO-66-F(4)precursor. All synthesized MOFs in this study were thoroughly characterized to verify formation of the desired MOF, porosity, crystallinity, and exchanged ligand content. This report represents a green, aqueous, room temperature synthesis of a highly valued series of Zr(iv)-based MOFs.

引用

页码：8841 / 8845

页数：5

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