Synthesis of Biaryls via Ligand-Free Suzuki-Miyaura Cross-Coupling Reactions: A Review of Homogeneous and Heterogeneous Catalytic Developments

被引：165

作者：

Hussain, Ibrar ^{[1
]}

Capricho, Jaworski ^{[2
]}

Yawer, Mirza A. ^{[3
]}

机构：

[1] Scion, Biopolymers & Chem Div, 49 Sala St,Private Bag 3020, Rotorua 3046, New Zealand

[2] Hex Pty Ltd, Gate 3,765 Ballarat Rd, Deer Pk, Vic 3023, Australia

[3] Res Ctr Tox Cpds Environm, Kamenice 753-5, Brno 62500, Czech Republic

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2016年 / 358卷 / 21期

关键词：

biaryls; ligand-free catalysis; nanoparticles; solid supports; Suzuki-Miyaura cross-coupling; FREE PALLADIUM CATALYSIS; HIGHLY-ACTIVE CATALYST; IN-SITU GENERATION; COMPLEX WOOL-PD; ROOM-TEMPERATURE; HECK REACTION; RECYCLABLE CATALYST; ARYL BROMIDES; SUPPORTED PALLADIUM; ARYLBORONIC ACIDS;

D O I：

10.1002/adsc.201600354

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This review describes the recent developments in the field of Suzuki-Miyaura cross-coupling reaction, in particular with regard to ligand-free catalysis. The catalysts outlined here allow convenient and green synthetic pathways specifically for the construction of C-C bonds. They enable the synthesis of biaryls by the coupling arylboronic acids with aryl halides. The literature reporting ligand-free synthesis of biaryls from 2010 to May 2015 has been reviewed.

引用

页码：3320 / 3349

页数：30

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