Charge and Energy Transfer Between CdSe Quantum Dots and Polyaniline

被引:5
作者
Xu, Liang [1 ]
Huang, Xingbin [1 ]
Dai, Wenjiang [1 ]
Sun, Punan [1 ]
Chen, Xuanlin [1 ]
An, Limin [1 ]
机构
[1] Heilongjiang Univ, Coll Phys Sci & Technol, Harbin 150080, Peoples R China
关键词
Quantum Dots (QDs); CdSe; Polyaniline (PAni); Fluorescence Life; Charge Transfer; Energy Transfer; LIGHT-EMITTING-DIODES; NANOCRYSTALS; PHOTOLUMINESCENCE; POLYMER;
D O I
10.1166/jnn.2016.11851
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CdSe quantum dots (QDs) and polyaniline (PAni) were mixed to prepare CdSe QDs/PAni complex. PAni can quench the fluorescence of CdSe QDs. Fluorescence intensity of CdSe QDs/PAni complex is related to the size of CdSe QDs and the concentration of PAni. UV-Vis absorption spectra, fluorescence spectra, time-resolved fluorescence spectroscopy were used to analys the quenching phenomenon. The mechanism of fluorescence quenching is dependent on two factors: on one hand, the Forster resonance energy transfer from CdSe to PAni; on the other hand, PAni can intercept the charge relaxation process of CdSe and lead to the interruption of radiative recombination.
引用
收藏
页码:3909 / 3913
页数:5
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