Flexible Bismuth Selenide/Graphene composite paper for lithium-ion batteries

被引:45
作者
Chen, Xinhang [1 ,2 ,3 ]
Tang, Hongli [1 ,2 ,3 ]
Huang, Zongyu [1 ,2 ,3 ]
Zhou, Jie [1 ,2 ,3 ]
Ren, Xiaohui [1 ,2 ,3 ]
Huang, Kai [1 ,2 ,3 ]
Qi, Xiang [1 ,2 ,3 ]
Zhong, Jianxin [1 ,2 ,3 ]
机构
[1] Xiangtan Univ, Hunan Key Lab Micronano Energy Mat & Devices, Xiangtan 411105, Hunan, Peoples R China
[2] Xiangtan Univ, Lab Quantum Engn & Micronano Energy Technol, Xiangtan 411105, Hunan, Peoples R China
[3] Xiangtan Univ, Sch Phys & Optoelect, Xiangtan 411105, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Bi2Se3; Graphene; Flexible; Binder-free; Lithium-ion battery; ELECTROCHEMICAL PERFORMANCE; SOLVOTHERMAL SYNTHESIS; GRAPHENE; NANOSHEETS; ELECTRODE; OXIDE; INTERCALATION; SEPARATOR; IMPEDANCE; INSERTION;
D O I
10.1016/j.ceramint.2016.10.110
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A flexible Bi2Se3/Graphene (BSG) composite paper has been prepared through a simple vacuum filtration method and a thermal reduction together. The BSG composite paper was directly used as anode electrode for lithium-ion batteries, without using any polymer binders or conduction additives. In contrast to the pure Bi2Se3, the BSG exhibits high reversible lithium ion storage capacities and superior cyclic capacity retention. It proposed that the superior lithium storage performances would be attributed to the special construction of the as-prepared BSG paper, in which the graphene can not only act as conductive network for electrodes, but also act as a frame to alleviate volume expansion or aggregation of Bi2Se3 nanosheets during lithiation/delithiation. The as-prepared BSG paper shows a great potential as an anode materials for flexible Li-ion batteries.
引用
收藏
页码:1437 / 1442
页数:6
相关论文
共 38 条
[1]   Effect of synthesis technique on electrochemical performance of bismuth selenide [J].
Ali, Zulfiqar ;
Cao, Chuanbao ;
Li, Jili ;
Wang, Yanli ;
Cao, Tai ;
Tanveer, M. ;
Tahir, Muhammad ;
Idrees, Faryal ;
Butt, Faheem K. .
JOURNAL OF POWER SOURCES, 2013, 229 :216-222
[2]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[3]   Lithium ions in the van der Waals gap of Bi2Se3 single crystals [J].
Bludska, J. ;
Jakubec, I. ;
Karamazov, S. ;
Horak, J. ;
Uher, C. .
JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (12) :2813-2817
[4]   Lithium intercalation into the tetradymite-type selenides Bi2-xInxSe3 [J].
Bludska, J ;
Jakubec, I ;
Lostak, P ;
Horak, J .
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1997, 76 (06) :867-873
[5]   Ultrafast Graphene Oxide Humidity Sensors [J].
Borini, Stefano ;
White, Richard ;
Wei, Di ;
Astley, Michael ;
Haque, Samiul ;
Spigone, Elisabetta ;
Harris, Nadine ;
Kivioja, Jani ;
Ryhanen, Tapani .
ACS NANO, 2013, 7 (12) :11166-11173
[6]   Electrochemical impedance study of Li-ion insertion into mesocarbon microbead single particle electrode Part II. Disordered carbon [J].
Dokko, K ;
Fujita, Y ;
Mohamedi, M ;
Umeda, M ;
Uchida, I ;
Selman, JR .
ELECTROCHIMICA ACTA, 2001, 47 (06) :933-938
[7]   A chemical route to graphene for device applications [J].
Gilje, Scott ;
Han, Song ;
Wang, Minsheng ;
Wang, Kang L. ;
Kaner, Richard B. .
NANO LETTERS, 2007, 7 (11) :3394-3398
[8]   In-doped Bi2Se3 hierarchical nanostructures as anode materials for Li-ion batteries [J].
Han, Guang ;
Chen, Zhi-Gang ;
Ye, Delai ;
Yang, Lei ;
Wang, Lianzhou ;
Drennan, John ;
Zou, Jin .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (19) :7109-7116
[9]   Electrochemical impedance of electrolyte/electrode interfaces of lithium-ion rechargeable batteries - Effects of additives to the electrolyte on negative electrode [J].
Itagaki, M ;
Yotsuda, S ;
Kobari, N ;
Watanabe, K ;
Kinoshita, S ;
Ue, M .
ELECTROCHIMICA ACTA, 2006, 51 (8-9) :1629-1635
[10]   Organic Solvent-Based Graphene Oxide Liquid Crystals: A Facile Route toward the Next Generation of Self-Assembled Layer-by-Layer Multifunctional 3D Architectures [J].
Jalili, Rouhollah ;
Aboutalebi, Seyed Hamed ;
Esrafilzadeh, Dorna ;
Konstantinov, Konstantin ;
Moulton, Simon E. ;
Razal, Joselito M. ;
Wallace, Gordon G. .
ACS NANO, 2013, 7 (05) :3981-3990