Synthesis and Crystal Structure of 6-Ethoxy-4′-chloro-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol

被引：0
作者：
Dong, W. -K. [1 ]
Xu, L. [1 ]
Dong, X. -Y. [1 ]
Li, G. [1 ]
Zhao, M. -M. [1 ]
Wu, J. -J. [1 ]
机构：
[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 17期
关键词：
Asymmetric Salamo-type compound; Synthesis; Crystal Structure; DNA-BINDING PROPERTIES; SPECTRAL PROPERTIES; MAGNETIC-PROPERTIES; COMPLEX SYNTHESIS; BISOXIME LIGAND; PHENOLATE; ZN(II);
D O I：
10.14233/ajchem.2013.15878
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The molecule of 6-ethoxy-4'-chloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol with the molecular formula C18H19N2O5Cl, adopts a V-shaped configuration, in which the benzene units are approximately perpendicular, making a dihedral angle of 78.97(3)degrees. Intramolecular H-bonds are formed between the OH groups and the oxime N atoms. In the crystal structure, each molecule links other neighbouring molecules by intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot pi hydrogen-bonding interactions into an infinite 1D supramolecular chain and the corresponging rectangular pore canal along a-axis.
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收藏
页码：9978 / 9980
页数：3
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