Catalytic application of silver nanoparticles immobilized to rice husk-SiO2-aminopropylsilane composite as recyclable catalyst in the aqueous reduction of nitroarenes

被引：49

作者：

Davarpanah, Jamal ^{[1
]}

Kiasat, Ali Reza ^{[1
]}

机构：

[1] Shahid Chamran Univ, Dept Chem, Coll Sci, Ahvaz 6135743169, Iran

来源：

CATALYSIS COMMUNICATIONS | 2013年 / 41卷

关键词：

Rice husk; Silver nanoparticles; Rice husk aminosilane; Nitro group reduction; PHASE-TRANSFER CATALYST; HETEROGENEOUS CATALYST; INCORPORATED SILICA; EFFICIENT ROUTE; HUSK; CONVERSION; POLYURETHANE; EPOXIDES; WATER;

D O I：

10.1016/j.catcom.2013.06.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In the present work, amorphous silica nanoparticles were taken from low-cost rice husk (RH-SiO2) by carrying out an acid chemical treatment followed by the process of burning. The nanoparticles were modified with aminopropyltrimethoxysilane (APTMS) using sol-gel method. The target nanocomposite (RHPrNH2@Ag) was formed by embedding the silver nanoparticles into the rice husk propylamine composite (RHPrNH2). The catalytic activity of RHPrNH2@Ag nanocomposite was successfully tested in the aqueous reduction of nitroarenes to the corresponding amines by using NaBH4 as reducing agent. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：6 / 11

页数：6

共 22 条

[1] Iron incorporated heterogeneous catalyst from rice husk ash
Adam, Farook
Kandasamy, Kalaivani
Balakrishnan, Saraswathy
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 304 (01) : 137 - 143
[2] The oxidation of styrene by chromium-silica heterogeneous catalyst prepared from rice husk
Adam, Farook
Iqbal, Anwar
[J]. CHEMICAL ENGINEERING JOURNAL, 2010, 160 (02) : 742 - 750
[3] The complete conversion of cyclohexane into cyclohexanol and cyclohexanone by a simple silica-chromium heterogeneous catalyst
Adam, Farook
Retnam, Premalatha
Iqbal, Anwar
[J]. APPLIED CATALYSIS A-GENERAL, 2009, 357 (01) : 93 - 99
[4] The immobilization of 3-(chloropropyl)triethoxysilane onto silica by a simple one-pot synthesis
Adam, Farook
Osman, Hasnah
Hello, Kasim Mohammed
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 331 (01) : 143 - 147
[5] Indium incorporated silica from rice husk and its catalytic activity
Ahmed, Adil Elhag
Adam, Farook
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 103 (1-3) : 284 - 295
[6] The benzylation of benzene using aluminium, gallium and iron incorporated silica from rice husk ash
Ahmed, Adil Elhag
Adam, Farook
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 118 (1-3) : 35 - 43
[7] Chary KP, 2000, SYNLETT, P683
[8] Fe3O4@PS@PAMAM-Ag Magnetic Nanocatalysts and Their Recoverable Catalytic Ability
Dang Gaofei
Shi Yan
Fu Zhifeng
Yang Wantai
[J]. CHINESE JOURNAL OF CATALYSIS, 2012, 33 (04) : 651 - 658
[9] Rice husk ash as an alternate source for active silica production
Della, VP
Kühn, I
Hotza, D
[J]. MATERIALS LETTERS, 2002, 57 (04) : 818 - 821
[10] HANNA SB, 1985, BRIT CERAM TRANS J, V84, P18

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