An Improved Protocol for Regioselective Ring-Opening of Sulfonyl Aziridines with Iodine Promoted by PPh3

被引：2
|
作者：
Zhang, Jinfeng [1 ]
Meng, Lingguo [1 ]
Li, Chuntao [1 ]
Xiao, Guoyuan [1 ]
机构：
[1] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Anhui, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2013年 / 31卷 / 12期
关键词：
sulfonyl aziridines; iodine; ring-opening; -iodo amines; PPh3; CARBON BOND-CLEAVAGE; TETRABUTYLAMMONIUM HALIDES; N-TOSYLAZIRIDINES; BETA-LACTAMS; EPOXIDES; CYCLOADDITION; EXPANSION; WATER; ISOMERIZATION; REACTIVITY;
D O I：
10.1002/cjoc.201300625
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new route to synthesize -iodo amines from sulfonyl aziridines and iodine was developed in the presence of PPh3. This ring-opening reaction was an efficient and simple process to give -iodo amines in excellent yields with high chemoselectivity.
引用
收藏
页码：1508 / 1512
页数：5
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