Highly Regioselective Preparation of 1,3-Dioxolane-4-methanol Derivatives from Glycerol Using Phosphomolybdic Acid

被引：5

作者：

Fadnavis, Nitin Wasantrao ^{[1
]}

Reddipalli, Gowri Sankar ^{[1
]}

Ramakrishna, Gadupudi ^{[1
]}

Mishra, Mithilesh Kumar ^{[1
]}

Sheelu, Gurrala ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Biotransformat Lab, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNTHESIS-STUTTGART | 2009年 / 04期

关键词：

glycerol; phosphomolybdic acid; complexation; regiospecificity; 1,3-dioxolane-4-methanol; REUSABLE CATALYST; SILICA-GEL; EFFICIENT; DEHYDRATION; ACROLEIN; MILD;

D O I：

10.1055/s-0028-1083319

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phosphomolybdic acid (PMA) forms a blue-colored complex with glycerol in 1:10 molar ratio. The glycerolato complex catalyzes conversion or glycerol into 1,3-dioxolane-4-methanol derivatives with complete regiospecificity in high yields (>95%) and the catalyst call be recycled up to tell times without loss of activity or regiospecificity.

引用

页码：557 / 560

页数：4

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