The increasing environmental awareness has directed attention of the researchers towards the field of natural fiber composites. The aim of this investigation is to understand the physico-chemical properties of fibers extracted from the bark of the Dichrostachys Cinerea (DC) plant. Dichrostachys Cinerea fibers (DCFs) has cellulose (72.4 wt. %), hemicellulose (13.08 wt. %), lignin (16.89 wt. %), density (1240 kg/m(3)), crystallinity index (57.82%), and tensile strength (873 +/- 14 MPa). Besides the cellulose degradation of DCFs at 359.3 degrees vide by the thermo-gravimetric analysis and chemical groups are identified by Fourier transform analysis. Eventually the characterization results of DCFs strongly show the possibility of reinforcement in polymer matrices.