Zwitterionic surfactants in ion binding and catalysis

被引:32
|
作者
Gerola, Adriana P. [1 ]
Costa, Paulo F. A. [1 ]
Quina, Frank H. [2 ]
Fiedler, Haidi D. [1 ]
Nome, Faruk [1 ]
机构
[1] Univ Fed Santa Catarina, INCT Catalise, Dept Quim, BR-88040900 Florianopolis, SC, Brazil
[2] Univ Sao Paulo, Inst Quim, BR-05508000 Sao Paulo, SP, Brazil
关键词
Zwitterionic surfactants; Chromatography; Electrophoresis; Cloud point extraction; Enzyme activity; Nanoparticles; catalysis; CAPILLARY-ELECTROPHORESIS; INORGANIC ANIONS; STATIONARY-PHASE; CARBOXYBETAINE SURFACTANT; SEPARATION SELECTIVITY; ELECTROOSMOTIC FLOW; MIXED SURFACTANTS; REVERSE MICELLES; CHROMATOGRAPHY; PROTEINS;
D O I
10.1016/j.cocis.2017.10.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Zwitterionic surfactants have unique properties for applications in separation methods and catalysis. Their properties and efficiencies depend on two main factors: surfactant structure and preferential interactions of zwitterionic surfactant interfaces with anions. Structural changes are related to hydrocarbon chain length, distance between charges, and type and order of functional groups in the polar head. Interactions of anions with zwitterionic micelles follow the Hofmeister series and change the surface charge. The interactions between surfactants and molecules/ions allow the rational control of separation by chromatography and micellar capillary electrophoresis; cloud point extraction; and stabilization and catalytic activity of biomolecules and nanoparticles. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:39 / 47
页数:9
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