A few fluorocarbon compounds (CFx)(n) were produced by the original thermo-gas-dynamic destruction (TD) of polytetrafluoroethylene (PTFE) at the high temperatures 530 and 550 degrees C. The chemical composition, electrochemical and morphological properties of such materials were characterized by electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM)/X-ray energy dispersive spectroscopy (XEDS) and compared to commercial fluorinated petroleum coke (CF1)(n). The possibility of the application of the new obtained compounds as the cathode materials in primary lithium batteries was estimated. The differences of the investigated samples properties, which observed during electrochemical tests, are discussed. (C) 2011 Published by Elsevier B.V Selection and/or peer-review under responsibility of Publication Committee of ASCO-NANOMAT 2011 and Far Eastern Federal University (FEFU)