Selective nitrogen doping in graphene for oxygen reduction reactions

被引:172
|
作者
Yasuda, Satoshi [1 ,2 ]
Yu, Li [1 ]
Kim, Jeheon [1 ]
Murakoshi, Kei [1 ]
机构
[1] Hokkaido Univ, Fac Sci, Dept Chem, Sapporo, Hokkaido 0600810, Japan
[2] Japan Sci & Technol Agcy, Kawaguchi, Saitama 3320012, Japan
关键词
DOPED GRAPHENE; ACTIVE-SITES; CATALYSTS; OXIDE;
D O I
10.1039/c3cc45641b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nitrogen-doped graphene materials with abundant pyridinic and quaternary nitrogen species were selectively synthesized by thermal surface polymerization of nitrogen-containing aromatic molecules. Catalytic studies revealed that the oxygen reduction by nitrogen-doped graphene, containing pyridinic and quaternary nitrogen species, proceeds via a four- and two-electron reduction pathway, respectively, in alkali-based solutions.
引用
收藏
页码:9627 / 9629
页数:3
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