Tetra-n-butylammonium bis(2,2-dicyanoethylene-1,1-dithiolato)palladium(II)

被引：1

作者：

Kanganga, Nyasha ^{[1
]}

Mann, Kent R. ^{[2
]}

Janzen, Daron E. ^{[1
]}

机构：

[1] Coll St Catherine, St Paul, MN 55105 USA

[2] Univ Minnesota, Minneapolis, MN 55455 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808037616

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, (C16H36N)(2)[Pd(C4N2S2)(2)], the Pd-II center adopts a distorted square-planar geometry due to the four-membered chelate rings formed by coordination of the 2,2-dicyanoethylene-1,1-dithiolate (i-mnt) ligands [bite angle 75.0159 (17)degrees]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the pi-system.

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页码：M1565 / U796

页数：10

相关论文

共 14 条

[1]

[Anonymous], SAINT

[2]

*BRUKER AXS INC, 2003, SMART SADABS

[3] Synthesis and characterization of a novel palladium(II) complex polymer having network structure with guest water molecules [J].

Cao, R ;

Su, WP ;

Hong, MC ;

Tatsumi, K .

CHEMISTRY LETTERS, 1999, (11) :1219-1220

[4]

Dong FY, 2005, INDIAN J CHEM A, V44, P1144

[5] SULFUR CHELATES .3. METAL COMPLEXES OF 1,1-DITHIOLATO ANIONS S2CS2-, S2CNCN2-, AND S2CC(CN)22- [J].

FACKLER, JP ;

COUCOUVA.D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (17) :3913-&

[6] Synthesis and crystal structures of group 10 metal bis(dithiolate) complexes constructed by 2,3-naphtho-15-crown-5 or 2,3-naphtho-18-crown-6 [J].

Gao, XK ;

Dou, JM ;

Li, DC ;

Dong, FY ;

Wang, DQ .

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2005, 53 (1-2) :111-119

[7] Synthesis and characterization of isomanolonitrile dithiolato palladium complexes. Crystal structure of (PPh3)(2)Pd(S2C4N2) and (Et4N)(2)WS4Pd(S2C4N2) [J].

Long, DL ;

Zheng, H ;

Xin, XQ ;

Sakane, G ;

Shibahara, T .

POLYHEDRON, 1997, 16 (24) :4305-4311

[8] Crown ether-half-capped sodium ions as bridges in the formation of complex polymer, structure of [{(benzo-15-crown-5)Na}2Pd(i-mnt)2]n {i-mnt = [S2C=C(CN)2]2-} [J].

Long, DL ;

Chen, JT ;

Cui, Y ;

Huang, JS .

CHEMISTRY LETTERS, 1998, (02) :171-172

[9] Syntheses and crystal structures of isomalononitrile dithiolato complexes (Bu(4)N)(2)Zn(i-mnt)(2) and (Et(4)N)(2)Pd(i-mnt)(2) [J].

Long, DL ;

Hou, HW ;

Xin, XQ ;

Yu, KB ;

Luo, BS ;

Chen, LR .

JOURNAL OF COORDINATION CHEMISTRY, 1996, 38 (1-2) :15-24

[10] PREPARATION, PROPERTIES, AND STRUCTURES OF PLANAR ANION COMPLEXES [J].

MORI, H ;

HIRABAYASHI, I ;

TANAKA, S ;

MORI, T ;

MARUYAMA, Y .

SYNTHETIC METALS, 1995, 70 (1-3) :1177-1178