Synthesis, crystal structure, and magnetic properties of bis(aqua) [μ(terepthalato-κo,κo′)]copper(II)monohydrate [Cu(C8O4)(OH2)2]•H2O

被引：2
作者：
Nfor, Emmanuel N. [1 ]
Majoumo-Mbe, Felicite [1 ]
Ndifon, Peter T. [2 ]
Duke, Emmanuel O. [3 ]
Mainsah, Evans N. [1 ]
Offiong, Offiong E. [3 ]
Eno, Ededet A. [3 ]
机构：
[1] Univ Buea, Dept Chem, Buea, Swr, Cameroon
[2] Univ Yaounde I, Coordinat Chem Lab, Dept Inorgan Chem, Yaounde, Cameroon
[3] Univ Calabar, Dept Pure & Appl Chem, Calabar, Crs, Nigeria
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2013年 / 201卷
关键词：
Cu(II) complex; Coordination polymer; Crystal structure; Magnetic properties; METAL-ORGANIC FRAMEWORKS; SINGLE-MOLECULE MAGNETS; END-ON AZIDO; COORDINATION POLYMERS; CHAIN COMPOUNDS; CARBOXYLATE; COMPLEX; LIGAND; CO; NICKEL(II);
D O I：
10.1016/j.jssc.2013.02.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel one dimensional Cu(II) coordination polymer [Cu(C8O4)(OH2)(2)]center dot H2O 1 has been synthesized and characterized by elemental analysis, IR spectroscopy, X-ray crystal diffraction and magnetic measurements. Single-crystal structural analysis shows that complex 1 consist of 1D Cu(II) chain containing threefold bridging ligands, one (syn-syn) carboxylate and two water molecules. The magnetic study of 1 has been investigated, indicating an overall antiferromagnetic interaction in the complex. (C) 2013 Elsevier Inc. All rights reserved.
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收藏
页码：133 / 136
页数：4
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