Characterization and catalytic performance of TiO2 nanotubes-supported gold and copper particles

被引:71
作者
Zhu, BL [1 ]
Guo, Q [1 ]
Huang, XL [1 ]
Wang, SR [1 ]
Zhang, SM [1 ]
Wu, SH [1 ]
Huang, WP [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
gold; copper; modified TiO2 nanotubes; catalytic performance; CO oxidation;
D O I
10.1016/j.molcata.2006.01.013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
TiO2 nanotubes are prepared via the reaction of anatase TiO, powder with NaOH solution. Gold and gold-copper supported on TiO, nanotubes (Au/TiO, NTs and Au-Cu/TiO2 NTs) are synthesized by deposition-precipitation method. The prepared materials are characterized with BET, powder X-ray diffraction (XRD), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). Their catalytic performance for low-temperature CO oxidation is studied by using a microreactor-GC system. The influence of support, pH of HAuCl4 solution, calcination temperature and atmosphere as well as gold content on the catalytic performance of Au/TiO2 NTs are investigated. Compared with AU/TiO2 NTs, the catalytic performance of Au-Cu/TiO2 NTs is better. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:211 / 217
页数:7
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