Solvatochromic properties of an ammonium containing polysilane in water-ethanol binary mixtures

被引：12
作者：
Seki, T
Tohnai, A
Tamaki, T
Kaito, A
机构：
[1] CATALYSTS & CHEM IND CO LTD, FINE CHEM RES CTR, WAKAMATSU KU, KITAKYUSHU, FUKUOKA 808, JAPAN
[2] NATL INST MAT & CHEM RES, TSUKUBA, IBARAKI 305, JAPAN
来源：
CHEMISTRY LETTERS | 1996年 / 05期
关键词：
D O I：
10.1246/cl.1996.361
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A water-soluble polysilane having a trimethylammonium group has been synthesized and its spectroscopic properties in water, ethanol and their binary mixtures are investigated. In water-ethanol binary mixtures, variations in the UV absorption and fluorescence properties attributed to the delocalized sigma electron in the Si backbone exhibit a maximum at intermediate mixing ratios.
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页码：361 / 362
页数：2
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