The effect of the geometry and content of the modified carbon nanotubes on the thermal properties of the composite phase-change materials

被引:7
|
作者
Li, Min [1 ,2 ]
Chen, Qiwen [1 ]
Yang, Caiqian [3 ]
机构
[1] Southeast Univ, Jiangsu Key Lab Construct Mat, Nanjing 211189, Peoples R China
[2] Minist Educ, Engn Res Ctr Bldg Equipment Energy & Environm, Nanjing 210096, Peoples R China
[3] Xiangtan Univ, Coll Civil Engn & Mech, Xiangtan 411100, Peoples R China
基金
中国国家自然科学基金;
关键词
MWNTs; Modification; Thermal property; Phase-change materials; ENERGY-STORAGE; HEAT-TRANSFER; CONDUCTIVITY; DISPERSION; ENHANCEMENT; PERFORMANCE; IMPROVEMENT; PCM;
D O I
10.1007/s10973-019-09177-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
In this paper, ultrasonic dispersion and surface chemical modification were used to prepare the modified multi-walled carbon nanotubes (MWNTs)/paraffin composite phase-change materials (PCMs). The surface modification of MWNTs was developed via coating MWNTs with silica dioxide. The modified MWNTs were marked as SiO2@MWNTs. The phase-change properties, thermal stability and chemical functional groups of the MWNTs/paraffin composite PCMs were measured by differential scanning calorimetry, thermogravimetric analysis (TG) and Fourier transform infrared spectroscopy, respectively. The results indicated that paraffin and MWNTs were compound physically. The diameter and content of MWNTs had influence on the phase-change temperature and the latent heat of the MWNTs/paraffin composite PCMs. The smaller the diameter or larger content of the SiO2@MWNTs, the greater the influence was. The reduction degree of PCM1(the diameter of the SiO2@MWNTs is 20-30 nm) in latent heat is about 4.5 times of that of PCM3(the diameter of the SiO2@MWNTs is larger than 50 nm). The thermal stability and the thermal conductivity of the composite PCMs were improved with the addition of the SiO2@MWNTs. When the content of SiO2@MWNTs is 5 mass%, the thermal conductivity of the paraffin PCMs is 0.383 W m(-1) K-1).
引用
收藏
页码:103 / 112
页数:10
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