Recent progress in biocatalysis using supercritical carbon dioxide

被引：66
|
作者：
Matsuda, Tomoko [1 ]
机构：
[1] Tokyo Inst Technol, Grad Sch Biosci & Biotechnol, Dept Bioengn, Midori Ku, Yokohama, Kanagawa 2268501, Japan
来源：
JOURNAL OF BIOSCIENCE AND BIOENGINEERING | 2013年 / 115卷 / 03期
关键词：
Supercritical fluid; Carbon dioxide; Biocatalysis; Enzyme; Organic synthesis; Asymmetric synthesis; Candida antarctica lipase B; Novozym; 435; Geotrichum candidum; Alcohol dehydrogenase; LIPASE-CATALYZED ESTERIFICATION; CONTINUOUS KINETIC RESOLUTION; ELECTROCHEMICAL CONVERSION; ASYMMETRIC REDUCTION; ENZYMATIC CATALYSIS; FLUOROUS SOLVENTS; ENANTIOSELECTIVITY; DECARBOXYLASE; PURIFICATION; TEMPERATURE;
D O I：
10.1016/j.jbiosc.2012.10.002
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
The latest advances in biocatalysis using supercritical carbon dioxide (scCO(2)) are reviewed. Stability and stabilization methodologies of enzymes in scCO(2) as well as reactions for organic synthesis are described. Especially, varieties of examples for lipase-catalyzed synthesis of chiral compounds using scCO(2) are given. Furthermore, asymmetric reduction by alcohol dehydrogenase in scCO(2) and carboxylation by decarboxylase in scCO(2) are also introduced. (C) 2012, The Society for Biotechnology, Japan. All rights reserved.
引用
收藏
页码：233 / 241
页数：9
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