Rhodium-catalyzed tandem Pauson-Khand type reactions of 1,4-enynes tethered by a cyclopropyl group

被引：20

作者：

Chen, Gen-Qiang ^{[1
]}

Shi, Min ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 07期

基金：

中国国家自然科学基金;

关键词：

UNIQUE TETRASUBSTITUTED ALKENE; 5+2 CYCLOADDITION REACTIONS; INTRAMOLECULAR CYCLOADDITION; POLYCYCLIC COMPOUNDS; METAL; VINYLCYCLOPROPANES; 1ST; CYCLIZATION; COMPLEXES; ALLENES;

D O I：

10.1039/c2cc37587g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tandem Pauson-Khand type reactions of 1,4-enynes tethered by a cyclopropyl group with two molecules of CO proceed smoothly in the presence of [Rh(CO)(2)Cl](2) under a CO atmosphere to give the corresponding 6-hydroxy-2,3-dihydro-1H-inden-1-one derivatives in moderate yields under mild conditions.

引用

收藏

页码：698 / 700

页数：3

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