Selective C-Si Bond Formation through C-H Functionalization

被引：81

作者：

Sharma, Ritika ^{[1
]}

Kumar, Rakesh ^{[1
]}

Kumar, Inder ^{[1
]}

Singh, Bikram ^{[1
]}

Sharma, Upendra ^{[1
]}

机构：

[1] CSIR, Nat Prod Chem & Proc Dev Div, Inst Himalayan Bioresource Technol, Palampur 176061, Himachal Prades, India

来源：

SYNTHESIS-STUTTGART | 2015年 / 47卷 / 16期

关键词：

silylation; C-H activation; catalytic; metal-free; siloles; CATALYZED REGIOSELECTIVE SILYLATION; SILICON-CONTAINING COMPOUNDS; CARBON-HYDROGEN BONDS; DEHYDROGENATIVE SILYLATION; ORGANIC-SYNTHESIS; C(SP(3))-H BONDS; CLEAVAGE; IRIDIUM; ACTIVATION; HYDROSILANES;

D O I：

10.1055/s-0034-1380435

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silylation of hydrocarbons is one of the most important transformations due to the diverse application of organosilanes. Continuous progress is being made in organosilane synthesis particularly through direct C-H activation/functionalization. This minireview compiles various processes reported for C-Si bond formation from 2000-2014, through C-H activation/functionalization (proximal and remote) and metal-free approaches. 1 Introduction 2 C-Si Bond Formation through C-H Activation in Intermolecular Fashion 2.1 C-Si Bond Formation through Direct C(sp(2))-H Activation 2.2 C-Si Bond Formation through Directing Group Assisted C(sp(2))-H Activation 2.3 C-Si Bond Formation through sp(3) C-H Activation 3 C-Si Bond Formation through Proximal C-H Activation/Functionalization in Intramolecular Fashion 3.1 Intramolecular C-Si Bond Formation through C(sp(2))-H Activation 3.2Intramolecular C-Si Bond Formation through C(sp(3))-H Activation 4 Siloles Synthesis through Heteroannulation 5 C-Si Bond Formation through Remote C-H Activation 6 C-Si Bond Formation through C-O Bond Cleavage 7 Metal-Free Methods for C-Si Bond Formation 8 Summary and Outlook

引用

页码：2347 / 2366

页数：20

共 81 条

[1]

[Anonymous], 1992, COMPREHENSIVE HDB HY, DOI DOI 10.1016/C2009-0-11185-6

[2]

[Anonymous], J CHEM COMMUN

[3]

Bains W, 2003, CURR OPIN DRUG DISC, V6, P526

[4]

Barry A. J., 1950, USP, Patent No. 2499561