New Ferro- and Antiferromagnetic Complexes of Tridentate Azomethines with Copper

被引:16
作者
Burlov, A. S. [1 ]
Ikorskii, V. N. [2 ]
Nikolaevskii, S. A. [1 ]
Koshchienko, Yu. V. [1 ]
Vlasenko, V. G. [3 ]
Zubavichus, Ya. V. [4 ]
Uraev, A. I. [1 ]
Vasil'chenko, I. S. [1 ]
Garnovskii, D. A. [5 ]
Borodkin, G. S. [1 ]
Garnovskii, A. D. [1 ]
机构
[1] So Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia
[2] Russian Acad Sci, Siberian Branch, Int Tomog Ctr, Novosibirsk 630090, Russia
[3] So Fed Univ, Phys Res Inst, Rostov Na Donu 344090, Russia
[4] Russian Res Ctr, Kurashov Inst, Moscow 123182, Russia
[5] Russian Acad Sci, So Sci Ctr, Rostov Na Donu 344006, Russia
关键词
23;
D O I
10.1134/S0036023608100082
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Tridentate azomethine ligands with N2O4 and N-3 donor atoms and their copper complexes were synthesized and characterized. The dimeric structure of copper(II) chelates was confirmed by EXAFS studies. Complexes based on 2-tosylaminobenzaldehyde azomethines tend to undergo ferromagnetic exchange, whereas similar salicylaldehyde derivatives have antiferromagnetic exchange.
引用
收藏
页码:1566 / 1572
页数:7
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