New Ferro- and Antiferromagnetic Complexes of Tridentate Azomethines with Copper

被引：16

作者：

Burlov, A. S. ^{[1
]}

Ikorskii, V. N. ^{[2
]}

Nikolaevskii, S. A. ^{[1
]}

Koshchienko, Yu. V. ^{[1
]}

Vlasenko, V. G. ^{[3
]}

Zubavichus, Ya. V. ^{[4
]}

Uraev, A. I. ^{[1
]}

Vasil'chenko, I. S. ^{[1
]}

Garnovskii, D. A. ^{[5
]}

Borodkin, G. S. ^{[1
]}

Garnovskii, A. D. ^{[1
]}

机构：

[1] So Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

[2] Russian Acad Sci, Siberian Branch, Int Tomog Ctr, Novosibirsk 630090, Russia

[3] So Fed Univ, Phys Res Inst, Rostov Na Donu 344090, Russia

[4] Russian Res Ctr, Kurashov Inst, Moscow 123182, Russia

[5] Russian Acad Sci, So Sci Ctr, Rostov Na Donu 344006, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 53卷 / 10期

关键词：

23;

D O I：

10.1134/S0036023608100082

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tridentate azomethine ligands with N2O4 and N-3 donor atoms and their copper complexes were synthesized and characterized. The dimeric structure of copper(II) chelates was confirmed by EXAFS studies. Complexes based on 2-tosylaminobenzaldehyde azomethines tend to undergo ferromagnetic exchange, whereas similar salicylaldehyde derivatives have antiferromagnetic exchange.

引用

页码：1566 / 1572

页数：7

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