Formation of an unusual charge-transfer network from an ionic liquid

被引:8
作者
Del Sesto, RE [1 ]
Baker, GA [1 ]
Baker, SN [1 ]
Scott, BL [1 ]
Keizer, TS [1 ]
Burrell, AK [1 ]
McCleskey, TM [1 ]
机构
[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA
关键词
D O I
10.1039/b513893k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An intriguing and novel charge-transfer complex between dimethyldihydrophenazine and diethylviologen has been crystallized from an ionic liquid at room temperature, resulting in an interesting stacking motif of interrupted D center dot center dot center dot A center dot center dot center dot D type triads: efficient formation of the complex is seen within an ionic liquid and acetone, with the complex absorbing strongly across nearly the entire visible-NIR spectral region.
引用
收藏
页码:272 / 274
页数:3
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