Lift-off patterning of Ag nanowire/PEDOT:PSS composite films for transparent electrodes using a fluoropolymer structure

被引:18
作者
Kim, Myoung-Soo [1 ]
Lee, Da-Hyeok [1 ]
Kim, Ki-Bo [1 ]
Jung, Seok-Heon [2 ]
Lee, Jin-Kyun [2 ]
O, Beom-Hoan [1 ]
Lee, Seung-Gol [1 ]
Park, Se-Geun [1 ]
机构
[1] Inha Univ, Dept Informat Engn, Inchon 402751, South Korea
[2] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
基金
新加坡国家研究基金会;
关键词
Poly(1H; 1H; 2H; 2H-perfluorodecyl methacrylate); Micro-contact printing; Silver; Nanowire; Lift-off process; SILVER NANOWIRE ELECTRODES; HIGHLY TRANSPARENT; HYBRID FILMS; CARBON NANOTUBES; SOLAR-CELLS; NETWORK; POLYMER; RESISTANCE;
D O I
10.1016/j.tsf.2015.02.028
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper describes a lift-off method of Ag nanowire (Ag NW) patterning using a poly(1H, 1H, 2H, 2H-perfluorodecyl methacrylate) polymer (PFDMA) structure as a mask which is prepared by micro-contact printing. Unlike a conventional photoresist mask, the PFDMA polymer is inert to the dispersion solvent of Ag NW. In addition, the hydrofluoroether solvent used for removing the mask layer of patterned PFDMA films after Ag NW deposition does not chemically affect the polyethylene naphthalate (PEN) substrate or poly(3,4-ethylene dioxythiophene): poly(styrene sulfonate) (PEDOT:PSS) coated on Ag NW layer. In this method, Ag NW/PEDOT: PSS composite films were patterned and the effects of the hot-press method were examined to further improve the electrical and optical properties of the composite films. Moreover, the hot-press method at 110 degrees C has an advantage of applying low pressure to make Ag NW/PEDOT:PSS embedded into PEN films compared to that of pressing samples without heating. The ratio of resistance change of patterned and hot-pressed composite film was only below 1% after repeated bending test. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:100 / 105
页数:6
相关论文
共 29 条
[1]   Highly Conductive and Flexible Silver Nanowire-Based Microelectrodes on Biocompatible Hydrogel [J].
Ahn, Yumi ;
Lee, Hyungjin ;
Lee, Donghwa ;
Lee, Youngu .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (21) :18401-18407
[2]   Reversibly Stretchable Transparent Conductive Coatings of Spray-Deposited Silver Nanowires [J].
Akter, Tahmina ;
Kim, Woo Soo .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (04) :1855-1859
[3]   Annealing-free, flexible silver nanowire-polymer composite electrodes via a continuous two-step spray-coating method [J].
Choi, Dong Yun ;
Kang, Hyun Wook ;
Sung, Hyung Jin ;
Kim, Sang Soo .
NANOSCALE, 2013, 5 (03) :977-983
[4]   Smooth Nanowire/Polymer Composite Transparent Electrodes [J].
Gaynor, Whitney ;
Burkhard, George F. ;
McGehee, Michael D. ;
Peumans, Peter .
ADVANCED MATERIALS, 2011, 23 (26) :2905-2910
[5]   Rolling Silver Nanowire Electrodes: Simultaneously Addressing Adhesion, Roughness, and Conductivity [J].
Hauger, Tate C. ;
Al-Rafia, S. M. Ibrahim ;
Buriak, Jillian M. .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (23) :12663-12671
[6]   Solution-processed transparent electrodes [J].
Hecht, David S. ;
Kaner, Richard B. .
MRS BULLETIN, 2011, 36 (10) :749-755
[7]   Metal nanogrids, nanowires, and nanofibers for transparent electrodes [J].
Hu, Liangbing ;
Wu, Hui ;
Cui, Yi .
MRS BULLETIN, 2011, 36 (10) :760-765
[8]   Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire Electrodes [J].
Hu, Liangbing ;
Kim, Han Sun ;
Lee, Jung-Yong ;
Peumans, Peter ;
Cui, Yi .
ACS NANO, 2010, 4 (05) :2955-2963
[9]   Ag nanowire percolating network embedded in indium tin oxide nanoparticles for printable transparent conducting electrodes [J].
Jeong, Jin-A ;
Kim, Han-Ki .
APPLIED PHYSICS LETTERS, 2014, 104 (07)
[10]   Brush-painted flexible organic solar cells using highly transparent and flexible Ag nanowire network electrodes [J].
Kang, Sin-Bi ;
Noh, Yong-Jin ;
Na, Seok-In ;
Kim, Han-Ki .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2014, 122 :152-157