CLICK 'n' Sleep: Light-Switch Behavior of Triazole-Containing Tris(bipyridyl)ruthenium Complexes

被引：8
作者：
Braumueller, Markus [1 ]
Staniszewska, Magdalena [2 ]
Guthmuller, Julien [2 ]
Rau, Sven [1 ]
机构：
[1] Univ Ulm, Anorgan Chem 1, Albert Einstein Allee 11, D-89081 Ulm, Germany
[2] Gdansk Univ Technol, Fac Appl Phys & Math, Narutowicza 11-12, PL-80233 Gdansk, Poland
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 31期
关键词：
Click chemistry; Triazole; Light switch; Ruthenium; TDDFT calculations; DIPYRIDOPHENAZINE COMPLEXES; PHOTOELECTROCHEMICAL CELLS; METAL-COMPLEX; RUTHENIUM(II); 8-HYDROXYQUINOLINE; PHOTOPHYSICS; REDUCTION; DYES;
D O I：
10.1002/ejic.201600964
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A set of Ru-II complexes incorporating triazole subunits are presented. They show a solvent-dependent light-switch effect. Theoretical calculations revealed the excited states involved in the emission process. The findings are highly important for future design of light-switch sensors and suggest a severe restriction for functional photomolecular devices synthesized by CLICK chemistry.
引用
收藏
页码：4958 / 4963
页数：6
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